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- W4281951241 abstract "In this work, we present an efficient bifunctional electrocatalyst comprising iron-nickel (FeNi) alloy nanoparticles confined in nitrogen-doped carbon nanotubes (denoted FeNi-NCNT) for zinc-air batteries. The FeNi-NCNT electrocatalyst is fabricated by anion-exchange of nickel(II) ion/zinc(II) ion-2,4,6-tris-(di(pyridin-2-yl)amino)-1,3,5-triazine complex with ferricyanide anion followed by mixing with melamine and then carbonization. The resultant FeNi-NCNT electrocatalyst displays excellent bifunctional activity with a low reversible oxygen electrode index of 0.725 V. The rechargeable aqueous zinc-air battery fabricated with FeNi-NCNT air cathode manifests both high specific capacity (819 mAh g-1Zn at 5.0 mA cm-2) and long cycle life (1500 cycles/1000 h at 10 mA cm-2, 600 cycles/400 h at 25 mA cm-2, and 165 cycles/110 h at 50 mA cm-2). Moreover, flexible solid-state zinc-air battery assembled with FeNi-NCNT air cathode can deliver a specific capacity of 765 mAh g-1Zn at 5.0 mA cm-2, a power density of 84.8 mW cm-2, and a cycle life of 110 h (330 cycles) at 2.0 mA cm-2." @default.
- W4281951241 created "2022-06-13" @default.
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- W4281951241 date "2022-11-01" @default.
- W4281951241 modified "2023-09-24" @default.
- W4281951241 title "Iron-nickel alloy nanoparticles encapsulated in nitrogen-doped carbon nanotubes as efficient bifunctional electrocatalyst for rechargeable zinc-air batteries" @default.
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- W4281951241 doi "https://doi.org/10.1016/j.jcis.2022.06.042" @default.
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