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• W4281991385 abstract "An important challenge concerning thin-film composite (TFC) membranes in brine treatment is to increase their water permeance while maintaining salt rejection for desalination performance. Structural control of polyamide (PA) thin films is a key factor in improving the desalination performance. In this study, we employed a Langmuir–Schaefer technique to fabricate PA Langmuir monolayers by interfacial polymerization of m-phenylenediamine and trimesoyl chloride at the liquid–gas interface and deposition on polysulfone supports. This technique allows the fabrication of nanoscale-controlled PA multilayers (2.3 nm per layer) with a nano-channeled structure through repeated deposition. The nanochannels of PA thin-film multilayers were clarified using the neutron reflectivity technique. UV treatment facilitates the maintenance of water-permeable sites in the nanochannels, which increases the water permeance up to 203% without loss of salt rejection performance. • Nanochannel-structured polyamide multilayer membranes were fabricated using a Langmuir-Schaefer technique. • The neutron reflectivity and AFM techniqes was used to verify the presence of the nanochannels in the polyamide thin films. • Nanochannel-structured polyamide membranes facilitate to increase the water permeance without loss of salt rejection." @default.
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• W4281991385 date "2022-09-01" @default.
• W4281991385 modified "2023-10-16" @default.
• W4281991385 title "Polyamide thin films with nanochannel networks synthesized at the liquid–gas interface for water purification" @default.
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• W4281991385 doi "https://doi.org/10.1016/j.memsci.2022.120671" @default.
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