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• W4282022117 endingPage "6346" @default.
• W4282022117 startingPage "6333" @default.
• W4282022117 abstract "We identified a ternary hybrid catalyst system composed of an acridinium photoredox catalyst, a thiophosphoric imide (TPI) catalyst, and a titanium complex catalyst that promoted an intermolecular addition reaction of organic molecules with various ketones through sp3 C–H bond activation. The thiyl radical generated via single-electron oxidation of TPI by the excited photoredox catalyst abstracted a hydrogen atom from organic molecules such as toluene, benzyl alcohol, alkenes, aldehydes, and THF. The thus-generated carbon-centered radical species underwent addition to ketones and aldehydes. This intrinsically unfavorable step was promoted by single-electron reduction of the intermediate alkoxy radical by catalytically generated titanium(III) species. This reaction provided an efficient and straightforward route to a broad range of tertiary alcohols and was successfully applied to late-stage functionalization of drugs or their derivatives. The proposed mechanism was supported by both experimental and theoretical studies." @default.
• W4282022117 created "2022-06-13" @default.
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• W4282022117 date "2022-06-01" @default.
• W4282022117 modified "2023-10-16" @default.
• W4282022117 title "A Catalytic Alkylation of Ketones via <i>sp</i>³ C–H Bond Activation" @default.
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• W4282022117 doi "https://doi.org/10.1021/acs.joc.2c00603" @default.
• W4282022117 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35649206" @default.
• W4282022117 hasPublicationYear "2022" @default.
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