Matches in SemOpenAlex for { <https://semopenalex.org/work/W4282023606> ?p ?o ?g. }
- W4282023606 endingPage "7421" @default.
- W4282023606 startingPage "7413" @default.
- W4282023606 abstract "Aside from its prominent role in the excretory system, urea is also a known protein denaturant. Here, we characterize urea as it behaves in confined spaces of AOT (sodium bis(2-ethylhexyl) sulfosuccinate) reverse micelles as a model of tight, confined spaces found at the subcellular level. Dynamic light scattering revealed that low temperatures (275 K) caused the smallest of the reverse micelle sizes, w0 = 10, to destabilize and dramatically increase in apparent hydrodynamic diameter. We attribute this to urea embedded into the surfactant interface as confirmed by 2D 1H-NOESY NMR spectroscopy. This increase in size in turn caused the hydrogen exchange between urea and water within the nanosized reverse micelles to increase as measured by 1D EXSY-NMR. A minimal enlarging effect and no increase in hydrogen exchange were observed when aqueous urea was introduced into w0 = 15 or 20 reverse micelles, suggesting that this effect is unique to particularly small-diameter spaces (∼7 nm)." @default.
- W4282023606 created "2022-06-13" @default.
- W4282023606 creator A5005348091 @default.
- W4282023606 creator A5018744863 @default.
- W4282023606 date "2022-06-07" @default.
- W4282023606 modified "2023-10-16" @default.
- W4282023606 title "Urea Disrupts the AOT Reverse Micelle Structure at Low Temperatures" @default.
- W4282023606 cites W1966867774 @default.
- W4282023606 cites W1970305282 @default.
- W4282023606 cites W1971847312 @default.
- W4282023606 cites W1973174787 @default.
- W4282023606 cites W1975343756 @default.
- W4282023606 cites W1976224208 @default.
- W4282023606 cites W1976734814 @default.
- W4282023606 cites W1988602268 @default.
- W4282023606 cites W1991755779 @default.
- W4282023606 cites W1998353110 @default.
- W4282023606 cites W2018162565 @default.
- W4282023606 cites W2018858346 @default.
- W4282023606 cites W2019198368 @default.
- W4282023606 cites W2026076675 @default.
- W4282023606 cites W2030752362 @default.
- W4282023606 cites W2033782375 @default.
- W4282023606 cites W2044040297 @default.
- W4282023606 cites W2045933761 @default.
- W4282023606 cites W2049740050 @default.
- W4282023606 cites W2055823675 @default.
- W4282023606 cites W2068261998 @default.
- W4282023606 cites W2076221964 @default.
- W4282023606 cites W2078913419 @default.
- W4282023606 cites W2087424671 @default.
- W4282023606 cites W2087538458 @default.
- W4282023606 cites W2095451817 @default.
- W4282023606 cites W2106043217 @default.
- W4282023606 cites W2110073614 @default.
- W4282023606 cites W2133426976 @default.
- W4282023606 cites W2134155194 @default.
- W4282023606 cites W2135648644 @default.
- W4282023606 cites W2136004344 @default.
- W4282023606 cites W2137890896 @default.
- W4282023606 cites W2157687501 @default.
- W4282023606 cites W2319946187 @default.
- W4282023606 cites W2491145203 @default.
- W4282023606 cites W2531602391 @default.
- W4282023606 cites W2532854584 @default.
- W4282023606 cites W2767839701 @default.
- W4282023606 cites W2890548129 @default.
- W4282023606 cites W2940084266 @default.
- W4282023606 cites W2947763367 @default.
- W4282023606 cites W2991416145 @default.
- W4282023606 cites W2994362639 @default.
- W4282023606 cites W3097545773 @default.
- W4282023606 cites W3118500794 @default.
- W4282023606 cites W3148628636 @default.
- W4282023606 cites W3168142806 @default.
- W4282023606 cites W4221086044 @default.
- W4282023606 doi "https://doi.org/10.1021/acs.langmuir.2c00206" @default.
- W4282023606 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35671271" @default.
- W4282023606 hasPublicationYear "2022" @default.
- W4282023606 type Work @default.
- W4282023606 citedByCount "2" @default.
- W4282023606 countsByYear W42820236062022 @default.
- W4282023606 countsByYear W42820236062023 @default.
- W4282023606 crossrefType "journal-article" @default.
- W4282023606 hasAuthorship W4282023606A5005348091 @default.
- W4282023606 hasAuthorship W4282023606A5018744863 @default.
- W4282023606 hasConcept C11268172 @default.
- W4282023606 hasConcept C113196181 @default.
- W4282023606 hasConcept C121332964 @default.
- W4282023606 hasConcept C127413603 @default.
- W4282023606 hasConcept C14631669 @default.
- W4282023606 hasConcept C147789679 @default.
- W4282023606 hasConcept C155672457 @default.
- W4282023606 hasConcept C178790620 @default.
- W4282023606 hasConcept C179104552 @default.
- W4282023606 hasConcept C184651966 @default.
- W4282023606 hasConcept C185592680 @default.
- W4282023606 hasConcept C19549132 @default.
- W4282023606 hasConcept C2780365088 @default.
- W4282023606 hasConcept C32891209 @default.
- W4282023606 hasConcept C42360764 @default.
- W4282023606 hasConcept C43617362 @default.
- W4282023606 hasConcept C55493867 @default.
- W4282023606 hasConcept C58226133 @default.
- W4282023606 hasConcept C62520636 @default.
- W4282023606 hasConcept C71240020 @default.
- W4282023606 hasConcept C8010536 @default.
- W4282023606 hasConceptScore W4282023606C11268172 @default.
- W4282023606 hasConceptScore W4282023606C113196181 @default.
- W4282023606 hasConceptScore W4282023606C121332964 @default.
- W4282023606 hasConceptScore W4282023606C127413603 @default.
- W4282023606 hasConceptScore W4282023606C14631669 @default.
- W4282023606 hasConceptScore W4282023606C147789679 @default.
- W4282023606 hasConceptScore W4282023606C155672457 @default.
- W4282023606 hasConceptScore W4282023606C178790620 @default.
- W4282023606 hasConceptScore W4282023606C179104552 @default.
- W4282023606 hasConceptScore W4282023606C184651966 @default.
- W4282023606 hasConceptScore W4282023606C185592680 @default.