FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4282023794> ?p ?o ?g. }

• W4282023794 abstract "Metal-organic frameworks (MOFs) are promising platforms for heterogeneous tethering of molecular CO2 reduction electrocatalysts. Yet, to further understand electrocatalytic MOF systems, one also needs to consider their capability to fine-tune the immediate chemical environment of the active site, and thus affect its overall catalytic operation. Here, we show that electrostatic secondary-sphere functionalities enable substantial improvement of CO2 -to-CO conversion activity and selectivity. In situ Raman analysis reveal that immobilization of pendent positively-charged groups adjacent to MOF-residing Fe-porphyrin catalysts, stabilize weakly-bound CO intermediates, allowing their rapid release as catalytic products. Also, by varying the electrolyte's ionic strength, systematic regulation of electrostatic field magnitude was achieved, resulting in essentially 100 % CO selectivity. Thus, this concept provides a sensitive molecular-handle that adjust heterogeneous electrocatalysis on demand." @default.
• W4282023794 created "2022-06-13" @default.
• W4282023794 creator A5005608415 @default.
• W4282023794 creator A5014234142 @default.
• W4282023794 creator A5014582181 @default.
• W4282023794 creator A5041755694 @default.
• W4282023794 creator A5049692788 @default.
• W4282023794 creator A5051704715 @default.
• W4282023794 creator A5058374613 @default.
• W4282023794 creator A5073698535 @default.
• W4282023794 creator A5085963150 @default.
• W4282023794 date "2022-06-28" @default.
• W4282023794 modified "2023-10-17" @default.
• W4282023794 title "Electrostatic Secondary‐Sphere Interactions That Facilitate Rapid and Selective Electrocatalytic CO₂ Reduction in a Fe‐Porphyrin‐Based Metal–Organic Framework" @default.
• W4282023794 cites W1966165983 @default.
• W4282023794 cites W1976140766 @default.
• W4282023794 cites W1989295290 @default.
• W4282023794 cites W2004550299 @default.
• W4282023794 cites W2008686504 @default.
• W4282023794 cites W2022582494 @default.
• W4282023794 cites W2026639267 @default.
• W4282023794 cites W2028182782 @default.
• W4282023794 cites W2036452223 @default.
• W4282023794 cites W2051808592 @default.
• W4282023794 cites W2078122806 @default.
• W4282023794 cites W2091161882 @default.
• W4282023794 cites W2136071148 @default.
• W4282023794 cites W2141939342 @default.
• W4282023794 cites W2144577309 @default.
• W4282023794 cites W2201513017 @default.
• W4282023794 cites W2271796547 @default.
• W4282023794 cites W2281464866 @default.
• W4282023794 cites W2297401062 @default.
• W4282023794 cites W2320373747 @default.
• W4282023794 cites W2320625878 @default.
• W4282023794 cites W2322571666 @default.
• W4282023794 cites W2326096459 @default.
• W4282023794 cites W2340814919 @default.
• W4282023794 cites W2346495035 @default.
• W4282023794 cites W2514591683 @default.
• W4282023794 cites W2558998316 @default.
• W4282023794 cites W2598761550 @default.
• W4282023794 cites W2604559121 @default.
• W4282023794 cites W2755463012 @default.
• W4282023794 cites W2758008507 @default.
• W4282023794 cites W2768401476 @default.
• W4282023794 cites W2809869471 @default.
• W4282023794 cites W2898856659 @default.
• W4282023794 cites W2901429145 @default.
• W4282023794 cites W2903603858 @default.
• W4282023794 cites W2912515813 @default.
• W4282023794 cites W2939470916 @default.
• W4282023794 cites W2945448914 @default.
• W4282023794 cites W2951656665 @default.
• W4282023794 cites W2954749216 @default.
• W4282023794 cites W2973656319 @default.
• W4282023794 cites W2979887490 @default.
• W4282023794 cites W2981210402 @default.
• W4282023794 cites W2999892469 @default.
• W4282023794 cites W3000584101 @default.
• W4282023794 cites W3031187737 @default.
• W4282023794 cites W3036105398 @default.
• W4282023794 cites W3037692580 @default.
• W4282023794 cites W3038246330 @default.
• W4282023794 cites W3097342269 @default.
• W4282023794 cites W3098512537 @default.
• W4282023794 cites W3104581571 @default.
• W4282023794 cites W3113233278 @default.
• W4282023794 cites W3126547229 @default.
• W4282023794 cites W3137988319 @default.
• W4282023794 cites W3138042392 @default.
• W4282023794 cites W3195348757 @default.
• W4282023794 cites W3198062078 @default.
• W4282023794 cites W4220761288 @default.
• W4282023794 cites W4220960752 @default.
• W4282023794 cites W4230230087 @default.
• W4282023794 cites W4234961553 @default.
• W4282023794 cites W4236967387 @default.
• W4282023794 cites W4243316637 @default.
• W4282023794 cites W4282023794 @default.
• W4282023794 doi "https://doi.org/10.1002/anie.202206085" @default.
• W4282023794 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35674328" @default.
• W4282023794 hasPublicationYear "2022" @default.
• W4282023794 type Work @default.
• W4282023794 citedByCount "19" @default.
• W4282023794 countsByYear W42820237942022 @default.
• W4282023794 countsByYear W42820237942023 @default.
• W4282023794 crossrefType "journal-article" @default.
• W4282023794 hasAuthorship W4282023794A5005608415 @default.
• W4282023794 hasAuthorship W4282023794A5014234142 @default.
• W4282023794 hasAuthorship W4282023794A5014582181 @default.
• W4282023794 hasAuthorship W4282023794A5041755694 @default.
• W4282023794 hasAuthorship W4282023794A5049692788 @default.
• W4282023794 hasAuthorship W4282023794A5051704715 @default.
• W4282023794 hasAuthorship W4282023794A5058374613 @default.
• W4282023794 hasAuthorship W4282023794A5073698535 @default.
• W4282023794 hasAuthorship W4282023794A5085963150 @default.
• W4282023794 hasBestOaLocation W42820237941 @default.
• W4282023794 hasConcept C118792377 @default.
• W4282023794 hasConcept C127413603 @default.

• next