FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4282554313> ?p ?o ?g. }

• W4282554313 endingPage "7588" @default.
• W4282554313 startingPage "7579" @default.
• W4282554313 abstract "Acetylene hydrochlorination is the core reaction in vinyl chloride monomer (VCM) production. Ruthenium chloride (RuClx) has emerged as a promising nonmercury alternative to replace the supported mercuric chloride (HgCl2) catalysts. However, it has some obstacles such as low activity, coke deposition, and over-reduction of active ruthenium (Ru) species. In this study, we found that the cooperation of Cu(X) (X = 0, I, and II) enhanced both the acetylene (C2H2) conversion efficiency (>96%) and VCM selectivity (>97%). Notably, the anchored Cu(I) ions can promote the rapid C2H2 molecule adsorption through Cu(I)-alkynyl π-complexation with the side-on mode. Furthermore, the one-electron complementary redox cycle of Cu(I)/Cu(II) pairs contributed to the Ru(III)/Ru(IV) cycle in the catalytic process. Density functional theory calculation results indicated that the Ru–O–Cu coordination sites played a crucial role in the catalytic activity of the hydrochlorination reaction, and the migration of Cl* was identified as the rate-limiting step of the entire catalytic pathway. The bimetallic RuCu/AC catalyst guaranteed the continuity and high efficiency of the reaction. Moreover, for the long-term catalytic reaction over 100 h, the C2H2 conversion efficiency was only decreased by 1.46% due to the restriction of in situ coke formation. These findings provide guidance for designing efficient Ru-based catalysts and solutions for engineering applications to replace existing mercury-contained catalysts." @default.
• W4282554313 created "2022-06-14" @default.
• W4282554313 creator A5020501565 @default.
• W4282554313 creator A5030077298 @default.
• W4282554313 creator A5052702508 @default.
• W4282554313 creator A5068922502 @default.
• W4282554313 creator A5073552078 @default.
• W4282554313 creator A5076694134 @default.
• W4282554313 date "2022-06-13" @default.
• W4282554313 modified "2023-10-14" @default.
• W4282554313 title "Tunable Redox Cycle and Enhanced π-Complexation in Acetylene Hydrochlorination over RuCu Catalysts" @default.
• W4282554313 cites W1494046285 @default.
• W4282554313 cites W1883025471 @default.
• W4282554313 cites W1964268805 @default.
• W4282554313 cites W1973974483 @default.
• W4282554313 cites W1977604861 @default.
• W4282554313 cites W1982572286 @default.
• W4282554313 cites W1990301926 @default.
• W4282554313 cites W2050944260 @default.
• W4282554313 cites W2070019211 @default.
• W4282554313 cites W2081970455 @default.
• W4282554313 cites W2083891658 @default.
• W4282554313 cites W2091091786 @default.
• W4282554313 cites W2094709842 @default.
• W4282554313 cites W2123743291 @default.
• W4282554313 cites W2125559262 @default.
• W4282554313 cites W2126116939 @default.
• W4282554313 cites W2157411645 @default.
• W4282554313 cites W2274526167 @default.
• W4282554313 cites W2293917208 @default.
• W4282554313 cites W2316939166 @default.
• W4282554313 cites W2325601123 @default.
• W4282554313 cites W2326521008 @default.
• W4282554313 cites W2327451778 @default.
• W4282554313 cites W2330950195 @default.
• W4282554313 cites W2338727897 @default.
• W4282554313 cites W2342101405 @default.
• W4282554313 cites W2342487827 @default.
• W4282554313 cites W2573559268 @default.
• W4282554313 cites W2773743445 @default.
• W4282554313 cites W2811222604 @default.
• W4282554313 cites W2887421185 @default.
• W4282554313 cites W2901301225 @default.
• W4282554313 cites W2915351284 @default.
• W4282554313 cites W2919480310 @default.
• W4282554313 cites W2954407043 @default.
• W4282554313 cites W2965144881 @default.
• W4282554313 cites W2981575388 @default.
• W4282554313 cites W2990214058 @default.
• W4282554313 cites W2998852364 @default.
• W4282554313 cites W3035776149 @default.
• W4282554313 cites W3093486306 @default.
• W4282554313 cites W3160532116 @default.
• W4282554313 cites W3186331331 @default.
• W4282554313 cites W3194413894 @default.
• W4282554313 cites W3203261230 @default.
• W4282554313 cites W4206476554 @default.
• W4282554313 doi "https://doi.org/10.1021/acscatal.2c01559" @default.
• W4282554313 hasPublicationYear "2022" @default.
• W4282554313 type Work @default.
• W4282554313 citedByCount "7" @default.
• W4282554313 countsByYear W42825543132022 @default.
• W4282554313 countsByYear W42825543132023 @default.
• W4282554313 crossrefType "journal-article" @default.
• W4282554313 hasAuthorship W4282554313A5020501565 @default.
• W4282554313 hasAuthorship W4282554313A5030077298 @default.
• W4282554313 hasAuthorship W4282554313A5052702508 @default.
• W4282554313 hasAuthorship W4282554313A5068922502 @default.
• W4282554313 hasAuthorship W4282554313A5073552078 @default.
• W4282554313 hasAuthorship W4282554313A5076694134 @default.
• W4282554313 hasConcept C150394285 @default.
• W4282554313 hasConcept C15920480 @default.
• W4282554313 hasConcept C161790260 @default.
• W4282554313 hasConcept C178790620 @default.
• W4282554313 hasConcept C179104552 @default.
• W4282554313 hasConcept C185592680 @default.
• W4282554313 hasConcept C2777517455 @default.
• W4282554313 hasConcept C2778695967 @default.
• W4282554313 hasConcept C2781460079 @default.
• W4282554313 hasConcept C43411465 @default.
• W4282554313 hasConcept C521977710 @default.
• W4282554313 hasConcept C555196967 @default.
• W4282554313 hasConcept C55904794 @default.
• W4282554313 hasConcept C63338738 @default.
• W4282554313 hasConcept C75473681 @default.
• W4282554313 hasConceptScore W4282554313C150394285 @default.
• W4282554313 hasConceptScore W4282554313C15920480 @default.
• W4282554313 hasConceptScore W4282554313C161790260 @default.
• W4282554313 hasConceptScore W4282554313C178790620 @default.
• W4282554313 hasConceptScore W4282554313C179104552 @default.
• W4282554313 hasConceptScore W4282554313C185592680 @default.
• W4282554313 hasConceptScore W4282554313C2777517455 @default.
• W4282554313 hasConceptScore W4282554313C2778695967 @default.
• W4282554313 hasConceptScore W4282554313C2781460079 @default.
• W4282554313 hasConceptScore W4282554313C43411465 @default.
• W4282554313 hasConceptScore W4282554313C521977710 @default.
• W4282554313 hasConceptScore W4282554313C555196967 @default.
• W4282554313 hasConceptScore W4282554313C55904794 @default.

• next