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- W4282561412 abstract "Abstract In this study, two (HO)R 2 P→Pd(II)Cl 2 ←NHC precatalysts ( 1 s) were designed and synthesized. Using these precatalysts, unreactive aryl chlorides, benzyl chlorides, or benzoyl chlorides were highly efficiently converted to the desired products in three to tens of minutes at 35 °C. Upon deprotonation of 1 s, density‐functional theory calculations and electrospray ionization mass spectrometry revealed that NHC was dissociated from the deprotonated precatalysts. Although it is difficult to ascertain the NHC dissociated from Pd(II) or Pd(0) species, the proposed anionic (O − )R 2 P→Pd(II)Cl 2 species could be reduced using ethoxide to form Pd(0) catalytic species. The cation and anion functions of salt additives were systematically elucidated. The cation size could be used to modulate the catalytic properties of 1 s through outer‐sphere electrostatic interactions between the coordinated R 2 P(O − ) and alkali metal ions. Moreover, the basicity of base was proportional to the catalytic yields. This study introduces newly designed Pd(II) precatalysts with superb catalytic properties that are stable and remarkably efficient." @default.
- W4282561412 created "2022-06-14" @default.
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- W4282561412 date "2022-07-06" @default.
- W4282561412 modified "2023-10-12" @default.
- W4282561412 title "Reactivity‐Tunable Palladium Precatalysts with Favorable Catalytic Properties in Suzuki–Miyaura Cross‐Coupling Reactions" @default.
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- W4282561412 cites W1967826314 @default.
- W4282561412 cites W1978890358 @default.
- W4282561412 cites W1982870835 @default.
- W4282561412 cites W1985001026 @default.
- W4282561412 cites W1992996188 @default.
- W4282561412 cites W2003555872 @default.
- W4282561412 cites W2009441924 @default.
- W4282561412 cites W2012295833 @default.
- W4282561412 cites W2014898354 @default.
- W4282561412 cites W2016076296 @default.
- W4282561412 cites W2023353655 @default.
- W4282561412 cites W2024619129 @default.
- W4282561412 cites W2027369535 @default.
- W4282561412 cites W2036527833 @default.
- W4282561412 cites W2037753722 @default.
- W4282561412 cites W2046073176 @default.
- W4282561412 cites W2047787055 @default.
- W4282561412 cites W2050442697 @default.
- W4282561412 cites W2065614351 @default.
- W4282561412 cites W2067037371 @default.
- W4282561412 cites W2073341670 @default.
- W4282561412 cites W2076941569 @default.
- W4282561412 cites W2078050217 @default.
- W4282561412 cites W2078257228 @default.
- W4282561412 cites W2082284812 @default.
- W4282561412 cites W2087268808 @default.
- W4282561412 cites W2100789870 @default.
- W4282561412 cites W2102277202 @default.
- W4282561412 cites W2112061711 @default.
- W4282561412 cites W2116117944 @default.
- W4282561412 cites W2119016897 @default.
- W4282561412 cites W2126522319 @default.
- W4282561412 cites W2131914170 @default.
- W4282561412 cites W2132525235 @default.
- W4282561412 cites W2139409773 @default.
- W4282561412 cites W2141453896 @default.
- W4282561412 cites W2141665100 @default.
- W4282561412 cites W2145443414 @default.
- W4282561412 cites W2161265745 @default.
- W4282561412 cites W2192030633 @default.
- W4282561412 cites W2262835952 @default.
- W4282561412 cites W2278731984 @default.
- W4282561412 cites W2313046607 @default.
- W4282561412 cites W2316262109 @default.
- W4282561412 cites W2317645396 @default.
- W4282561412 cites W2331126116 @default.
- W4282561412 cites W2331297548 @default.
- W4282561412 cites W2418389840 @default.
- W4282561412 cites W2441091839 @default.
- W4282561412 cites W2511906707 @default.
- W4282561412 cites W2594380937 @default.
- W4282561412 cites W2606199146 @default.
- W4282561412 cites W2724551730 @default.
- W4282561412 cites W2754696738 @default.
- W4282561412 cites W2760474393 @default.
- W4282561412 cites W2765327383 @default.
- W4282561412 cites W2793980387 @default.
- W4282561412 cites W2794067849 @default.
- W4282561412 cites W2803216834 @default.
- W4282561412 cites W2890676278 @default.
- W4282561412 cites W2891603737 @default.
- W4282561412 cites W2897648366 @default.
- W4282561412 cites W2902896374 @default.
- W4282561412 cites W2919443340 @default.
- W4282561412 cites W2952297080 @default.
- W4282561412 cites W2993698780 @default.
- W4282561412 cites W3006828628 @default.
- W4282561412 cites W3029103958 @default.
- W4282561412 cites W3040170768 @default.
- W4282561412 cites W3043483907 @default.
- W4282561412 cites W3046856656 @default.
- W4282561412 cites W3046955628 @default.
- W4282561412 cites W3111196614 @default.
- W4282561412 cites W3179374802 @default.
- W4282561412 cites W3180128532 @default.
- W4282561412 cites W3181700418 @default.
- W4282561412 cites W3202658757 @default.
- W4282561412 cites W4210333034 @default.
- W4282561412 cites W4220674316 @default.
- W4282561412 cites W4234620227 @default.
- W4282561412 cites W4235464744 @default.
- W4282561412 cites W847886084 @default.
- W4282561412 doi "https://doi.org/10.1002/cctc.202200736" @default.
- W4282561412 hasPublicationYear "2022" @default.
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