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• W4282913583 endingPage "9466" @default.
• W4282913583 startingPage "9454" @default.
• W4282913583 abstract "A new rare-earth oxyborate Ba3BiPbEuO(BO3)4 was prepared, and its crystal structure was established by the single-crystal X-ray diffraction method with the following structural data: P63/mmc, a = 5.4305(1) Å, c = 26.3501(3) Å, V = 672.96(3) Å3 and Z = 2. This is a layered material containing two types of layers: one is formed by corner-sharing EuO6 octahedra and BO3 triangles and the other is composed of corner- or edge-sharing (Bi/Pb)O7 hexagonal pyramids and BO3 triangles. These layers and their equivalent partners are alternately stacked along the c-axis, with Ba2+ cations situated in between and within the layers. Furthermore, the phase composition, morphology, and IR, Raman, XPS, and UV-vis absorption spectra of this compound were studied. In addition, solid solutions of Ba3BiPbY1-xEuxO(BO3)4 (0 ≤ x ≤ 1) were prepared via the solid-state reaction method and their photoluminescence properties were investigated. Ba3BiPbYO(BO3)4 and Ba3BiPbEuO(BO3)4 showed blue and reddish-orange luminescence when excited at 242 and 394 nm, respectively. By doping Eu3+ into the Ba3BiPbYO(BO3)4 matrix and changing the Eu3+ doping concentration, luminescence color tunability from blue to orange-red was realized in Ba3BiPbY1-xEuxO(BO3)4 phosphors under excitation at 331 nm. This kind of material with color variability may have potential application in field-emission displays." @default.
• W4282913583 created "2022-06-16" @default.
• W4282913583 creator A5007640720 @default.
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• W4282913583 creator A5016646891 @default.
• W4282913583 date "2022-01-01" @default.
• W4282913583 modified "2023-09-26" @default.
• W4282913583 title "A new rare-earth oxyborate Ba₃BiPbEuO(BO₃)₄ and the luminescence properties of the Ba₃BiPbY_1−<i>x</i>Eu_<i>x</i>O(BO₃)₄ phosphors" @default.
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• W4282913583 doi "https://doi.org/10.1039/d2dt01063a" @default.
• W4282913583 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35678144" @default.
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