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- W4282924632 abstract "NMR spectroscopy can sometimes be hampered by two inherent weaknesses: low sensitivity and overlap of signals in complex mixtures. Hyperpolarisation techniques using para-hydrogen (including the method known as SABRE) can overcome this sensitivity problem, but cannot circumvent spectral overlap. Conversely, a recently described selective excitation technique (known as DREAMTIME) can overcome overlap in mixtures, but suffers from a decrease in sensitivity. Here we demonstrate the combination of these two methods in a single approach termed SABRE-DREAM, to selectively provide hyperpolarised signals of user-specified components of a chemical reaction, where otherwise overlapping 1H signals would hinder reaction monitoring or analysis." @default.
- W4282924632 created "2022-06-16" @default.
- W4282924632 creator A5028445818 @default.
- W4282924632 date "2022-01-01" @default.
- W4282924632 modified "2023-09-25" @default.
- W4282924632 title "Selective NMR detection of individual reaction components hyperpolarised by reversible exchange with para-hydrogen" @default.
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- W4282924632 doi "https://doi.org/10.1039/d2cp01657e" @default.
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