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• W4282928942 abstract "Described herein is a B(C6 F5 )3 -catalyzed S-H insertion reaction of thiophenols and thiols with α-diazoesters to access valuable α-thioesters. With the established protocol, an array of α-thioester products are generated in moderate to good yields with broad scope and functional group tolerance. In addition, this reaction maintains its high efficiency on gram scale and the product can be easily transformed into other useful motifs. This reaction proceeds under solvent-free conditions at room temperature, and generally finishes in twenty minutes upon magnet stirring, which offers an expedient way for the synthesis of thioether-containing compounds." @default.
• W4282928942 created "2022-06-16" @default.
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• W4282928942 date "2022-06-28" @default.
• W4282928942 modified "2023-10-16" @default.
• W4282928942 title "Solvent‐free, B(C ₆ F ₅ ) ₃ ‐Catalyzed S−H Insertion of Thiophenols and Thiols with α‐Diazoesters" @default.
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• W4282928942 doi "https://doi.org/10.1002/asia.202200465" @default.
• W4282928942 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35678551" @default.
• W4282928942 hasPublicationYear "2022" @default.
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