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- W4282930022 abstract "Despite many important industrial applications, epoxy resin (EP) suffers from high flammability and toxicity emission, extremely hampering their applications. To circumvent the problem, core–shell structured ZIF67@ZIF8 is successfully synthesized and further functionalized with phytic acid (PA) to obtain PA-ZIF67@ZIF8 hybrids. Then, it is used as an efficient flame retardant to reduce the fire risk of EP. The fire test results show a significant reduction in heat and smoke production. Compared with EP, incorporating 5.0 wt % PA-ZIF67@ZIF8 into EP, the peak heat release rate, total heat release, and peak carbon monoxide production are dramatically reduced by 42.2, 33.0, and 41.5%, respectively. Moreover, the EP/PA-ZIF67@ZIF8 composites achieve the UL-94 V-0 rating and the limiting oxygen index increases by 29.3%. These superior fire safety properties are mainly attributed to the excellent dispersion and the catalytic effect of metal oxide and phosphorus-containing compounds. This work provides an efficient strategy for preparing a promising ZIF-based flame retardant for enhancing flame retardancy and smoke toxicity suppression of EP." @default.
- W4282930022 created "2022-06-16" @default.
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- W4282930022 date "2022-06-14" @default.
- W4282930022 modified "2023-10-16" @default.
- W4282930022 title "Core–Shell ZIF67@ZIF8 Modified with Phytic Acid as an Effective Flame Retardant for Improving the Fire Safety of Epoxy Resins" @default.
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- W4282930022 doi "https://doi.org/10.1021/acsomega.2c01545" @default.
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