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- W4282942371 abstract "C-aryl glycosides are popular basic skeletons in biochemistry and pharmaceutical chemistry. Herein, ruthenium-catalyzed highly stereo- and site-selective ortho- and meta-CAr -H glycosylation is described. A series of C-aryl pyranosides and furanosides were synthesized by this method. The strategy showed good substrate scope, and various N-heterocyclic directing groups were compatible with the reaction system. A mechanistic study suggested that the key pathway of ortho-CAr -H glycosylation might involve oxidative addition/reduction elimination, whereas aryl meta-C-H glycosylation was mediated by σ-activation. Density functional theory calculations also showed that the high stereoselectivity of meta-CAr -H glycosylation was due to steric hindrance." @default.
- W4282942371 created "2022-06-16" @default.
- W4282942371 creator A5021887595 @default.
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- W4282942371 date "2022-06-28" @default.
- W4282942371 modified "2023-10-16" @default.
- W4282942371 title "Ruthenium‐Catalyzed Stereo‐ and Site‐Selective <i>ortho‐</i> and <i>meta</i> ‐C−H Glycosylation and Mechanistic Studies" @default.
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