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• W4282971376 abstract "Abstract Recently, novel C 5 ‐position‐unprotected mesoionic N ‐heterocyclic olefins (mNHOs) demonstrated interesting reactivity with various Lewis acids during experiments. In this work, extensive DFT calculations show that the isomerization of such mNHOs to more Lewis‐basic mesoionic carbenes (MICs) can be efficiently catalyzed by weakly protic acidic species including C 5 ‐unprotected mNHOs, their Lewis adducts and polar H 2 O molecules, thus enabling catalytic isomerization and H‐isotope exchange of such mNHOs and their Lewis adducts." @default.
• W4282971376 created "2022-06-17" @default.
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• W4282971376 date "2022-07-14" @default.
• W4282971376 modified "2023-10-18" @default.
• W4282971376 title "Catalytic Isomerization of Unprotected Mesoionic <i>N</i>‐Heterocyclic Olefins and Their Lewis Adducts" @default.
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• W4282971376 doi "https://doi.org/10.1002/ejoc.202200539" @default.
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