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- W4283010129 endingPage "112051" @default.
- W4283010129 startingPage "112051" @default.
- W4283010129 abstract "Purposive regulation of the spatial location and distribution of acid sites in a zeolite catalyst, though still rather challenging, has proved to be an effective measure to enhance its performance in the conversion of methanol to olefins (MTO). Herein, a series of ZSM-11 zeolites were synthesized using different sodium halides (with tetrabutylammonium hydroxide (TBAOH) as the structure-directing agent); the effect of halogen anions (Cl-, Br- and I-) in the synthesis gel on the Al siting and thereon the spatial location and distribution of acid sites in the ZSM-11 zeolites as well as their relation to the catalytic performance in MTO was elaborately investigated. The results indicate that for the synthesis of high Si/Al ratio ZSM-11 zeolites (Si/Al > 60), the Cl- anions present in the synthesis gel can induce more Al atoms siting on the external surface of ZSM-11 crystals, thereby leading to a short catalytic lifetime in MTO due to the rapid coke deposition. In contrast, larger Br- or I- anions in the synthesis gel, owing to their stronger covalent interaction with the TBA+ cations, may moderate the formation of crystal silicate nuclei and lead to a uniform distribution of Al species in the inner straight channels, which can effectively suppress the surface coke deposition and inhibit the aromatic-based cycle for MTO. As a result, the high Si/Al ratio ZSM-11 zeolites obtained with Br- or I- in the synthesis gel exhibit much better catalytic stability in MTO and higher selectivity to propene and butene, in comparison with the ZSM-11 counterpart synthesized using Cl-. These results help to clarify the relation between the catalytic performance of ZSM-11 in MTO and the location of acid sites and thus bring forward a facile strategy to enhance the catalytic performance of zeolites through purposively regulating the spatial distribution of acid sites." @default.
- W4283010129 created "2022-06-18" @default.
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- W4283010129 date "2022-08-01" @default.
- W4283010129 modified "2023-10-03" @default.
- W4283010129 title "Regulating the distribution of acid sites in ZSM-11 zeolite with different halogen anions to enhance its catalytic performance in the conversion of methanol to olefins" @default.
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- W4283010129 doi "https://doi.org/10.1016/j.micromeso.2022.112051" @default.
- W4283010129 hasPublicationYear "2022" @default.
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