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- W4283025731 endingPage "3882" @default.
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- W4283025731 abstract "The stabilising effect of benzannulation on isoindenes formed in the course of sigmatropic shifts of (C5H5)Fe(CO)2 or of organo-silyl groups, and on exocyclic allyl intermediates in the course of haptotropic shifts of organometallic fragments over polycyclic skeletons (fluorene, cyclopenta[def]phenanthrene, syn and anti dibenzpentalenes) is exemplified. This approach led to the development of the first organometallic molecular brake. Benzyne cycloadditions to anthracenes to form triptycenes also led to unexpected or multiple adducts that were characterised by X-ray crystallography. Synthetic routes to the previously elusive benz[cd]azulene system are presented. Finally, the complete mechanism of the stepwise assembly of dispiro- and diindenyltetracenes from fluorenylallenes is presented, whereby every intermediate has been unambiguously structurally characterised." @default.
- W4283025731 created "2022-06-18" @default.
- W4283025731 creator A5032391697 @default.
- W4283025731 date "2022-06-17" @default.
- W4283025731 modified "2023-09-30" @default.
- W4283025731 title "The Effect of Benzannulation on the Structures, Reactivity and Molecular Dynamics of Indenes, Pentalenes, Azulenes and Related Molecules" @default.
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- W4283025731 doi "https://doi.org/10.3390/molecules27123882" @default.
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