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- W4283155894 abstract "The widely investigated oxygen reduction reaction (ORR) is well-known to proceed via two competing routes, involving two or four electrons, and yielding different reaction products, respectively. Both pathways are believed to share a common, elusive intermediate, namely, the hydroperoxyl radical. By exploiting a cobalt single-atom biomimetic model catalyst, based on a self-assembled monolayer of Co-porphyrins grown on an almost free-standing graphene sheet, we identify, in situ at room temperature in O2+H2O atmosphere, a hydroperoxyl-water cluster that is stabilized at the Co single-metal atom catalytic site. We show that the interplay between charge transfer, dipole and H-bonding, and water solvation behavior actually determines the hydroperoxyl-water complex stability, the Co-OOH bonding geometry, and, prospectively, opens to the engineered control of the selectivity of ORR pathways." @default.
- W4283155894 created "2022-06-21" @default.
- W4283155894 creator A5001625595 @default.
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- W4283155894 date "2022-06-20" @default.
- W4283155894 modified "2023-09-25" @default.
- W4283155894 title "Single Metal Atom Catalysts and ORR: H-Bonding, Solvation, and the Elusive Hydroperoxyl Intermediate" @default.
- W4283155894 cites W1111865340 @default.
- W4283155894 cites W1942429332 @default.
- W4283155894 cites W1959200120 @default.
- W4283155894 cites W1965818086 @default.
- W4283155894 cites W1966949133 @default.
- W4283155894 cites W1973214628 @default.
- W4283155894 cites W1979087321 @default.
- W4283155894 cites W1993631124 @default.
- W4283155894 cites W1996285904 @default.
- W4283155894 cites W1998260542 @default.
- W4283155894 cites W2002512844 @default.
- W4283155894 cites W2003271076 @default.
- W4283155894 cites W2012121428 @default.
- W4283155894 cites W2018400997 @default.
- W4283155894 cites W2018658360 @default.
- W4283155894 cites W2019852705 @default.
- W4283155894 cites W2043691039 @default.
- W4283155894 cites W2049880389 @default.
- W4283155894 cites W2053930414 @default.
- W4283155894 cites W2055465627 @default.
- W4283155894 cites W2057586961 @default.
- W4283155894 cites W2064807075 @default.
- W4283155894 cites W2068285722 @default.
- W4283155894 cites W2068893462 @default.
- W4283155894 cites W2072687598 @default.
- W4283155894 cites W2081759844 @default.
- W4283155894 cites W2082484285 @default.
- W4283155894 cites W2092157292 @default.
- W4283155894 cites W2093609678 @default.
- W4283155894 cites W2094128396 @default.
- W4283155894 cites W2094371959 @default.
- W4283155894 cites W2098547240 @default.
- W4283155894 cites W2101650618 @default.
- W4283155894 cites W2120145199 @default.
- W4283155894 cites W2129349842 @default.
- W4283155894 cites W2153543052 @default.
- W4283155894 cites W2209652843 @default.
- W4283155894 cites W2265316890 @default.
- W4283155894 cites W2278279172 @default.
- W4283155894 cites W2290645004 @default.
- W4283155894 cites W2293011067 @default.
- W4283155894 cites W2308580910 @default.
- W4283155894 cites W2315968939 @default.
- W4283155894 cites W2320475142 @default.
- W4283155894 cites W2324859472 @default.
- W4283155894 cites W2329552138 @default.
- W4283155894 cites W2329760721 @default.
- W4283155894 cites W2338744545 @default.
- W4283155894 cites W2394985542 @default.
- W4283155894 cites W2506242350 @default.
- W4283155894 cites W2519219719 @default.
- W4283155894 cites W2623295634 @default.
- W4283155894 cites W2624455063 @default.
- W4283155894 cites W2764180565 @default.
- W4283155894 cites W2778341989 @default.
- W4283155894 cites W2896383256 @default.
- W4283155894 cites W2899179078 @default.
- W4283155894 cites W2900504521 @default.
- W4283155894 cites W2901462587 @default.
- W4283155894 cites W2902366601 @default.
- W4283155894 cites W2912076539 @default.
- W4283155894 cites W2953614403 @default.
- W4283155894 cites W2995646383 @default.
- W4283155894 cites W2997066310 @default.
- W4283155894 cites W2999090610 @default.
- W4283155894 cites W2999951339 @default.
- W4283155894 cites W3004642305 @default.
- W4283155894 cites W3007104701 @default.
- W4283155894 cites W3010347562 @default.
- W4283155894 cites W3014083603 @default.
- W4283155894 cites W3042156029 @default.
- W4283155894 cites W3043858592 @default.
- W4283155894 cites W3101095095 @default.
- W4283155894 cites W3114432452 @default.
- W4283155894 cites W3120258290 @default.
- W4283155894 cites W3127944590 @default.
- W4283155894 cites W3129115126 @default.
- W4283155894 cites W3130284703 @default.
- W4283155894 cites W3154418318 @default.
- W4283155894 cites W3155612668 @default.
- W4283155894 cites W3170230429 @default.
- W4283155894 cites W3193608265 @default.