Matches in SemOpenAlex for { <https://semopenalex.org/work/W4283170385> ?p ?o ?g. }
- W4283170385 abstract "Abstract The insertion copolymerization of polar olefins and ethylene remains a significant challenge in part due to catalysts′ low activity and poor thermal stability. Herein we demonstrate a strategy toward addressing these obstacles through ligand design. Neutral nickel phosphine enolate catalysts with large phosphine substituents reaching the axial positions of Ni achieve activity of up to 7.7×10 3 kg mol −1 h −1 (efficiency >35×10 3 g copolymer/g Ni) at 110 °C, notable for ethylene/acrylate copolymerization. NMR analysis of resulting copolymers reveals highly linear microstructures with main‐chain ester functionality. Structure‐performance studies indicate a strong correlation between axial steric hindrance and catalyst performance." @default.
- W4283170385 created "2022-06-21" @default.
- W4283170385 creator A5004911977 @default.
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- W4283170385 creator A5086195107 @default.
- W4283170385 creator A5086755096 @default.
- W4283170385 date "2022-07-18" @default.
- W4283170385 modified "2023-10-17" @default.
- W4283170385 title "Highly Active and Thermally Robust Nickel Enolate Catalysts for the Synthesis of Ethylene‐Acrylate Copolymers" @default.
- W4283170385 cites W1793873404 @default.
- W4283170385 cites W1969681255 @default.
- W4283170385 cites W1973210652 @default.
- W4283170385 cites W1979699202 @default.
- W4283170385 cites W1983171316 @default.
- W4283170385 cites W1986119632 @default.
- W4283170385 cites W1987500317 @default.
- W4283170385 cites W1991819754 @default.
- W4283170385 cites W1993469265 @default.
- W4283170385 cites W1993736232 @default.
- W4283170385 cites W2006156000 @default.
- W4283170385 cites W2008964226 @default.
- W4283170385 cites W2012591289 @default.
- W4283170385 cites W2013464543 @default.
- W4283170385 cites W2016689740 @default.
- W4283170385 cites W2023768893 @default.
- W4283170385 cites W2026367143 @default.
- W4283170385 cites W2032811039 @default.
- W4283170385 cites W2034483067 @default.
- W4283170385 cites W2035412467 @default.
- W4283170385 cites W2035438145 @default.
- W4283170385 cites W2041002131 @default.
- W4283170385 cites W2049499358 @default.
- W4283170385 cites W2058950539 @default.
- W4283170385 cites W2068054822 @default.
- W4283170385 cites W2074515805 @default.
- W4283170385 cites W2081674162 @default.
- W4283170385 cites W2082455140 @default.
- W4283170385 cites W2082860639 @default.
- W4283170385 cites W2085888042 @default.
- W4283170385 cites W2088221767 @default.
- W4283170385 cites W2089908251 @default.
- W4283170385 cites W2093262399 @default.
- W4283170385 cites W2095069219 @default.
- W4283170385 cites W2097984738 @default.
- W4283170385 cites W2100300015 @default.
- W4283170385 cites W2100896869 @default.
- W4283170385 cites W2105475848 @default.
- W4283170385 cites W2109189427 @default.
- W4283170385 cites W2119207439 @default.
- W4283170385 cites W2134145857 @default.
- W4283170385 cites W2134913810 @default.
- W4283170385 cites W2148960065 @default.
- W4283170385 cites W2220708213 @default.
- W4283170385 cites W2260375281 @default.
- W4283170385 cites W2262047238 @default.
- W4283170385 cites W2262172625 @default.
- W4283170385 cites W2315746341 @default.
- W4283170385 cites W2320085780 @default.
- W4283170385 cites W2326456169 @default.
- W4283170385 cites W2329687435 @default.
- W4283170385 cites W2346557320 @default.
- W4283170385 cites W2467400748 @default.
- W4283170385 cites W2517731926 @default.
- W4283170385 cites W2519460947 @default.
- W4283170385 cites W2579497072 @default.
- W4283170385 cites W2589560949 @default.
- W4283170385 cites W2735559645 @default.
- W4283170385 cites W2757940636 @default.
- W4283170385 cites W2758303344 @default.
- W4283170385 cites W2769136989 @default.
- W4283170385 cites W2793818091 @default.
- W4283170385 cites W2802481704 @default.
- W4283170385 cites W2804268262 @default.
- W4283170385 cites W2810235481 @default.
- W4283170385 cites W2884055569 @default.
- W4283170385 cites W2901948818 @default.
- W4283170385 cites W2912154445 @default.
- W4283170385 cites W2971791401 @default.
- W4283170385 cites W2979413242 @default.
- W4283170385 cites W2991383024 @default.
- W4283170385 cites W2999979591 @default.
- W4283170385 cites W3012362614 @default.
- W4283170385 cites W3013767435 @default.
- W4283170385 cites W3014229153 @default.
- W4283170385 cites W3014908342 @default.
- W4283170385 cites W3027877407 @default.
- W4283170385 cites W3046462852 @default.
- W4283170385 cites W3081742766 @default.
- W4283170385 cites W3102160430 @default.
- W4283170385 cites W3111160006 @default.
- W4283170385 cites W3129352010 @default.
- W4283170385 cites W3129379107 @default.
- W4283170385 cites W3153631957 @default.
- W4283170385 cites W3165696094 @default.
- W4283170385 cites W3165836961 @default.
- W4283170385 cites W3190237582 @default.
- W4283170385 cites W3193879646 @default.