Matches in SemOpenAlex for { <https://semopenalex.org/work/W4283213545> ?p ?o ?g. }
- W4283213545 endingPage "4568" @default.
- W4283213545 startingPage "4563" @default.
- W4283213545 abstract "Direct asymmetric alkyl group functionalizations can potentially convert abundant and inexpensive hydrocarbon feedstocks into value-added chiral fine chemicals. Here, we report a one-pot, dehydrogenation-based strategy for enantioselective formal benzylic C(sp3)-H bond borylation. Dehydrogenation of alkylarenes by a pincer-Ir complex produces aryl alkenes via a tandem dehydrogenation/alkene-isomerization catalysis. The subsequent Cu-catalyzed asymmetric alkene hydroboration affords benzylic boronate esters with excellent site- and enantioselectivity. The generality of this strategy has been further demonstrated by asymmetric alkyl group amination." @default.
- W4283213545 created "2022-06-22" @default.
- W4283213545 creator A5019165702 @default.
- W4283213545 creator A5033486450 @default.
- W4283213545 creator A5033734116 @default.
- W4283213545 creator A5037644447 @default.
- W4283213545 creator A5087118452 @default.
- W4283213545 date "2022-06-20" @default.
- W4283213545 modified "2023-10-18" @default.
- W4283213545 title "Undirected, Asymmetric Alkyl Group Functionalizations through Alkane Dehydrogenation" @default.
- W4283213545 cites W1508677297 @default.
- W4283213545 cites W1967662782 @default.
- W4283213545 cites W1971584560 @default.
- W4283213545 cites W1979418547 @default.
- W4283213545 cites W2005661768 @default.
- W4283213545 cites W2006630058 @default.
- W4283213545 cites W2017255626 @default.
- W4283213545 cites W2041860183 @default.
- W4283213545 cites W2044856595 @default.
- W4283213545 cites W2050359473 @default.
- W4283213545 cites W2060176306 @default.
- W4283213545 cites W2081521474 @default.
- W4283213545 cites W2082039974 @default.
- W4283213545 cites W2083150093 @default.
- W4283213545 cites W2111894677 @default.
- W4283213545 cites W2137694358 @default.
- W4283213545 cites W2149950922 @default.
- W4283213545 cites W2153848081 @default.
- W4283213545 cites W2158930657 @default.
- W4283213545 cites W2172719425 @default.
- W4283213545 cites W2200631345 @default.
- W4283213545 cites W2253330152 @default.
- W4283213545 cites W2317059881 @default.
- W4283213545 cites W2320517364 @default.
- W4283213545 cites W2324208632 @default.
- W4283213545 cites W2328705110 @default.
- W4283213545 cites W2333819813 @default.
- W4283213545 cites W2346072123 @default.
- W4283213545 cites W2379591351 @default.
- W4283213545 cites W2444352686 @default.
- W4283213545 cites W2515068481 @default.
- W4283213545 cites W2515342784 @default.
- W4283213545 cites W2540439680 @default.
- W4283213545 cites W2601224882 @default.
- W4283213545 cites W2616080101 @default.
- W4283213545 cites W2617140651 @default.
- W4283213545 cites W2757887969 @default.
- W4283213545 cites W2767304235 @default.
- W4283213545 cites W2769205387 @default.
- W4283213545 cites W2777651827 @default.
- W4283213545 cites W2787869092 @default.
- W4283213545 cites W2793216085 @default.
- W4283213545 cites W2890987253 @default.
- W4283213545 cites W2891713085 @default.
- W4283213545 cites W2919132289 @default.
- W4283213545 cites W2924942953 @default.
- W4283213545 cites W2936837998 @default.
- W4283213545 cites W2955754338 @default.
- W4283213545 cites W2965344939 @default.
- W4283213545 cites W2995891480 @default.
- W4283213545 cites W3026121095 @default.
- W4283213545 cites W3036579042 @default.
- W4283213545 cites W3093279035 @default.
- W4283213545 cites W3100755484 @default.
- W4283213545 cites W3127981401 @default.
- W4283213545 cites W3160001948 @default.
- W4283213545 doi "https://doi.org/10.1021/acs.orglett.2c01009" @default.
- W4283213545 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35724678" @default.
- W4283213545 hasPublicationYear "2022" @default.
- W4283213545 type Work @default.
- W4283213545 citedByCount "1" @default.
- W4283213545 countsByYear W42832135452023 @default.
- W4283213545 crossrefType "journal-article" @default.
- W4283213545 hasAuthorship W4283213545A5019165702 @default.
- W4283213545 hasAuthorship W4283213545A5033486450 @default.
- W4283213545 hasAuthorship W4283213545A5033734116 @default.
- W4283213545 hasAuthorship W4283213545A5037644447 @default.
- W4283213545 hasAuthorship W4283213545A5087118452 @default.
- W4283213545 hasConcept C119889771 @default.
- W4283213545 hasConcept C146686406 @default.
- W4283213545 hasConcept C161790260 @default.
- W4283213545 hasConcept C178790620 @default.
- W4283213545 hasConcept C185592680 @default.
- W4283213545 hasConcept C196306401 @default.
- W4283213545 hasConcept C21951064 @default.
- W4283213545 hasConcept C2776254738 @default.
- W4283213545 hasConcept C2776413204 @default.
- W4283213545 hasConcept C2780263894 @default.
- W4283213545 hasConcept C2781076698 @default.
- W4283213545 hasConcept C2781327020 @default.
- W4283213545 hasConceptScore W4283213545C119889771 @default.
- W4283213545 hasConceptScore W4283213545C146686406 @default.
- W4283213545 hasConceptScore W4283213545C161790260 @default.
- W4283213545 hasConceptScore W4283213545C178790620 @default.
- W4283213545 hasConceptScore W4283213545C185592680 @default.
- W4283213545 hasConceptScore W4283213545C196306401 @default.
- W4283213545 hasConceptScore W4283213545C21951064 @default.
- W4283213545 hasConceptScore W4283213545C2776254738 @default.