Matches in SemOpenAlex for { <https://semopenalex.org/work/W4283263266> ?p ?o ?g. }
- W4283263266 endingPage "137743" @default.
- W4283263266 startingPage "137743" @default.
- W4283263266 abstract "The poor interfacial contact and notorious instability issues between solid electrolyte and electrodes seriously handicap the practical applications of solid-state lithium metal batteries (LMBs). In-situ polymerization is a considerable choice to upgrade the interfacial transport properties by directly curing the liquid precursor inside the cell. Herein, a ∼ 17 μm poly(ethylene glycol) methyl ether methacrylate (PEGMEA) based solid polymer electrolyte (SPE) is prepared by this method. Trimethyl phosphate (TMP) and LiNO3 are introduced to promote the ion transport as well as enhance the electrodes/electrolyte interfacial stability. Interestingly, although LiNO3 increases the electrolyte’s glass transition temperature thus hinders the anion transport, while higher Li+ conductivity is obtained due to the weakened interaction between Li+ and its ligands, ethylene oxide (EO) and TMP. The optimal electrolyte (PTLiN1) shows an acceptable ionic conductivity of 1.2 × 10-4 S cm−1 at 55°C and lithium ion transference number (tLi+) of 0.46, which enables the Li||Li symmetric cells to run stability within 1500 h (0.2 mA cm−2, 0.4 mAh cm−2) at 55°C and 1000 h (0.1 mA cm−2, 0.2 mAh cm−2) at 25°C. Meanwhile, the LiFePO4||Li cell with PTLiN1 shows superior long cycle lifetime with a high capacity retention of 88.4% over 300 cycles at 0.5 C. The cells coupled with LiCoO2 can even work stably under room temperature in the voltage range of 3.0 ∼ 4.3 V. Pouch cells based on PTLiN1 are also prepared and show outstanding flexibility and high security, which provides new idea for the development of economical and convenient solid-state batteries." @default.
- W4283263266 created "2022-06-23" @default.
- W4283263266 creator A5003547177 @default.
- W4283263266 creator A5018991047 @default.
- W4283263266 creator A5021636467 @default.
- W4283263266 creator A5022513578 @default.
- W4283263266 creator A5036505593 @default.
- W4283263266 creator A5083489326 @default.
- W4283263266 creator A5090437378 @default.
- W4283263266 date "2022-11-01" @default.
- W4283263266 modified "2023-10-03" @default.
- W4283263266 title "LiNO3 and TMP enabled high voltage room-temperature solid-state lithium metal battery" @default.
- W4283263266 cites W2061039743 @default.
- W4283263266 cites W2510883737 @default.
- W4283263266 cites W2593815020 @default.
- W4283263266 cites W2768314275 @default.
- W4283263266 cites W2811122284 @default.
- W4283263266 cites W2884761132 @default.
- W4283263266 cites W2887725221 @default.
- W4283263266 cites W2899922052 @default.
- W4283263266 cites W2921202963 @default.
- W4283263266 cites W2947156241 @default.
- W4283263266 cites W2956415704 @default.
- W4283263266 cites W2964780530 @default.
- W4283263266 cites W2965804259 @default.
- W4283263266 cites W3005783238 @default.
- W4283263266 cites W3006362419 @default.
- W4283263266 cites W3007447726 @default.
- W4283263266 cites W3011946342 @default.
- W4283263266 cites W3013862396 @default.
- W4283263266 cites W3016389065 @default.
- W4283263266 cites W3022689334 @default.
- W4283263266 cites W3037308705 @default.
- W4283263266 cites W3038591351 @default.
- W4283263266 cites W3082518462 @default.
- W4283263266 cites W3093258551 @default.
- W4283263266 cites W3134729790 @default.
- W4283263266 cites W3143907294 @default.
- W4283263266 cites W3157037866 @default.
- W4283263266 cites W3157934864 @default.
- W4283263266 cites W3160916040 @default.
- W4283263266 cites W3189504715 @default.
- W4283263266 cites W3208803215 @default.
- W4283263266 cites W4205735178 @default.
- W4283263266 cites W4210523713 @default.
- W4283263266 cites W4212941738 @default.
- W4283263266 cites W4223481119 @default.
- W4283263266 cites W4224223987 @default.
- W4283263266 cites W4249274243 @default.
- W4283263266 cites W4281490426 @default.
- W4283263266 cites W4283385658 @default.
- W4283263266 doi "https://doi.org/10.1016/j.cej.2022.137743" @default.
- W4283263266 hasPublicationYear "2022" @default.
- W4283263266 type Work @default.
- W4283263266 citedByCount "4" @default.
- W4283263266 countsByYear W42832632662023 @default.
- W4283263266 crossrefType "journal-article" @default.
- W4283263266 hasAuthorship W4283263266A5003547177 @default.
- W4283263266 hasAuthorship W4283263266A5018991047 @default.
- W4283263266 hasAuthorship W4283263266A5021636467 @default.
- W4283263266 hasAuthorship W4283263266A5022513578 @default.
- W4283263266 hasAuthorship W4283263266A5036505593 @default.
- W4283263266 hasAuthorship W4283263266A5083489326 @default.
- W4283263266 hasAuthorship W4283263266A5090437378 @default.
- W4283263266 hasConcept C122865956 @default.
- W4283263266 hasConcept C127413603 @default.
- W4283263266 hasConcept C131540310 @default.
- W4283263266 hasConcept C134018914 @default.
- W4283263266 hasConcept C138679309 @default.
- W4283263266 hasConcept C147789679 @default.
- W4283263266 hasConcept C15920480 @default.
- W4283263266 hasConcept C159985019 @default.
- W4283263266 hasConcept C17525397 @default.
- W4283263266 hasConcept C185592680 @default.
- W4283263266 hasConcept C192562407 @default.
- W4283263266 hasConcept C2777516009 @default.
- W4283263266 hasConcept C2777801237 @default.
- W4283263266 hasConcept C2778541603 @default.
- W4283263266 hasConcept C42360764 @default.
- W4283263266 hasConcept C521977710 @default.
- W4283263266 hasConcept C68801617 @default.
- W4283263266 hasConcept C71924100 @default.
- W4283263266 hasConceptScore W4283263266C122865956 @default.
- W4283263266 hasConceptScore W4283263266C127413603 @default.
- W4283263266 hasConceptScore W4283263266C131540310 @default.
- W4283263266 hasConceptScore W4283263266C134018914 @default.
- W4283263266 hasConceptScore W4283263266C138679309 @default.
- W4283263266 hasConceptScore W4283263266C147789679 @default.
- W4283263266 hasConceptScore W4283263266C15920480 @default.
- W4283263266 hasConceptScore W4283263266C159985019 @default.
- W4283263266 hasConceptScore W4283263266C17525397 @default.
- W4283263266 hasConceptScore W4283263266C185592680 @default.
- W4283263266 hasConceptScore W4283263266C192562407 @default.
- W4283263266 hasConceptScore W4283263266C2777516009 @default.
- W4283263266 hasConceptScore W4283263266C2777801237 @default.
- W4283263266 hasConceptScore W4283263266C2778541603 @default.
- W4283263266 hasConceptScore W4283263266C42360764 @default.
- W4283263266 hasConceptScore W4283263266C521977710 @default.