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- W4283269079 abstract "• Hydroxyethyl group would decrease the effectiveness of biogas upgrading. • Hydroxyethyl group can reduce the energy consumption of the regeneration process. • Hydroxyethyl group would not reduce CO 2 /CH 4 selectivity of MEA derivative. • Amino group exhibited superior effects on biogas upgrading than hydroxyl group. • Initial CO 2 uptake rate decreased significantly when the H bond on the amino group was completely replaced by the hydroxyethyl group. Upgrading of biogas to produce biomethane is an essential way to increase the calorific value of biogas by separating CH 4 and CO 2 to satisfy the global renewable energy demand. In this study, the efficiency of carbon dioxide (CO 2 ) trapping in aqueous monoethanolamine (MEA), diglycolamine (DGA), diethanolamine (DEA), and triethanolamine (TEA) solution during biogas upgrading for biomethane was determined. Effects of hydroxyethyl groups on MEA derivatives were investigated in terms of biogas upgrading and regeneration, CO 2 desorption heat, initial CO 2 absorption rate and CO 2 /CH 4 selectivity. The duration of upgraded biogas meeting certain European Union (EU) application standards for methane purity during upgrading was reduced by 70, 78 and 200 mins for DGA, DEA and TEA respectively compared to MEA due to the partial substitution of H-bonds by hydroxyethyl groups, and the absorption rate was also reduced, whereas TEA was not suitable for biogas upgrading as it was inefficient for biogas upgrading effect and absorption rate. The calculated results from the Gibbs-Helmholtz equation showed that MEA had the largest CO 2 desorption heat (82.47 kJ/mol CO 2 ) and the other MEA derivatives had lower desorption heat than MEA, indicating that MEA consumes more energy in the desorption process. As for the equilibrium partial pressure, all amine solutions absorbed less than 0.4% of the total volume of CH 4 and had a high CO 2 /CH 4 selectivity." @default.
- W4283269079 created "2022-06-23" @default.
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- W4283269079 date "2022-10-01" @default.
- W4283269079 modified "2023-10-16" @default.
- W4283269079 title "Effects of hydroxyethyl group on monoethanolamine (MEA) derivatives for biomethane from biogas upgrading" @default.
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- W4283269079 doi "https://doi.org/10.1016/j.fuel.2022.124874" @default.
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