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- W4283271520 abstract "An efficient and novel approach to accessing 3-selenylquinolines from diaryl diselenides and acyclic, selenium-free substrates is described. Preliminary mechanistic studies indicate that the combination of CuCl2 and air affords an appropriate environment for producing arylselenyl radicals that initiate the cascade cyclization of N-(2-alkynyl)anilines, forming key Se-C and C-C bonds in a single step. Using this chemistry, a wide variety of 3-selenylquinolines were produced in moderate to excellent yield under mild conditions, highlighting the versatility and usefulness of this new method." @default.
- W4283271520 created "2022-06-23" @default.
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- W4283271520 date "2022-06-22" @default.
- W4283271520 modified "2023-10-12" @default.
- W4283271520 title "Arylselenyl Radical-Mediated Cyclization of <i>N</i>-(2-Alkynyl)anilines: Access to 3-Selenylquinolines" @default.
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- W4283271520 doi "https://doi.org/10.1021/acs.joc.2c00282" @default.
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