FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4283277583> ?p ?o ?g. }

• W4283277583 endingPage "8389" @default.
• W4283277583 startingPage "8380" @default.
• W4283277583 abstract "C(aryl)-OMe bond functionalization catalyzed by cobalt(II) chloride in combination with a nacnac-type ligand and magnesium as a reductant is reported. Borylation and benzoylation of aryl methoxides are demonstrated, and C(aryl)-SMe bond borylation can be achieved under similar conditions. This is the first example of achieving these transformations using cobalt catalysis. Mechanistic studies suggest that a Grignard reagent is generated as an intermediate in a rare example of a magnesiation via a C-O bond activation reaction. Indeed, an organomagnesium species could be directly observed by electrospray ionization mass spectroscopic analysis. Kinetic experiments indicate that a heterogeneous cobalt catalyst performs the C-O bond activation." @default.
• W4283277583 created "2022-06-23" @default.
• W4283277583 creator A5012920150 @default.
• W4283277583 creator A5024699424 @default.
• W4283277583 creator A5026896088 @default.
• W4283277583 creator A5060796492 @default.
• W4283277583 creator A5064413649 @default.
• W4283277583 creator A5076619486 @default.
• W4283277583 creator A5085521599 @default.
• W4283277583 date "2022-06-22" @default.
• W4283277583 modified "2023-10-12" @default.
• W4283277583 title "Cobalt-Catalyzed Formation of Grignard Reagents <i>via</i> C–O or C–S Bond Activation" @default.
• W4283277583 cites W1134712535 @default.
• W4283277583 cites W1260922102 @default.
• W4283277583 cites W1494811621 @default.
• W4283277583 cites W1540699572 @default.
• W4283277583 cites W1822548149 @default.
• W4283277583 cites W1963547169 @default.
• W4283277583 cites W1966805055 @default.
• W4283277583 cites W1966937884 @default.
• W4283277583 cites W1970800627 @default.
• W4283277583 cites W1970866898 @default.
• W4283277583 cites W1971907948 @default.
• W4283277583 cites W1975036644 @default.
• W4283277583 cites W1975574833 @default.
• W4283277583 cites W1975885062 @default.
• W4283277583 cites W1977573785 @default.
• W4283277583 cites W1982121142 @default.
• W4283277583 cites W1983708544 @default.
• W4283277583 cites W1989226389 @default.
• W4283277583 cites W1997791324 @default.
• W4283277583 cites W2002215002 @default.
• W4283277583 cites W2007504235 @default.
• W4283277583 cites W2013805457 @default.
• W4283277583 cites W2014900705 @default.
• W4283277583 cites W2018635908 @default.
• W4283277583 cites W2022078013 @default.
• W4283277583 cites W2030502830 @default.
• W4283277583 cites W2037560749 @default.
• W4283277583 cites W2038808854 @default.
• W4283277583 cites W2044899369 @default.
• W4283277583 cites W2044927816 @default.
• W4283277583 cites W2044951714 @default.
• W4283277583 cites W2046143876 @default.
• W4283277583 cites W2046375331 @default.
• W4283277583 cites W2051691158 @default.
• W4283277583 cites W2062565741 @default.
• W4283277583 cites W2069086764 @default.
• W4283277583 cites W2074166183 @default.
• W4283277583 cites W2078406212 @default.
• W4283277583 cites W2080702699 @default.
• W4283277583 cites W2094927387 @default.
• W4283277583 cites W2098665439 @default.
• W4283277583 cites W2099615748 @default.
• W4283277583 cites W2104502392 @default.
• W4283277583 cites W2104884894 @default.
• W4283277583 cites W2112375301 @default.
• W4283277583 cites W2112629797 @default.
• W4283277583 cites W2120347191 @default.
• W4283277583 cites W2127732535 @default.
• W4283277583 cites W2128793374 @default.
• W4283277583 cites W2130251918 @default.
• W4283277583 cites W2131048607 @default.
• W4283277583 cites W2131210504 @default.
• W4283277583 cites W2134734845 @default.
• W4283277583 cites W2135026158 @default.
• W4283277583 cites W2145365726 @default.
• W4283277583 cites W2146837742 @default.
• W4283277583 cites W2147122698 @default.
• W4283277583 cites W2149915758 @default.
• W4283277583 cites W2152204735 @default.
• W4283277583 cites W2163598571 @default.
• W4283277583 cites W2174137318 @default.
• W4283277583 cites W2180674680 @default.
• W4283277583 cites W2246336468 @default.
• W4283277583 cites W2264043886 @default.
• W4283277583 cites W2281650513 @default.
• W4283277583 cites W2307580311 @default.
• W4283277583 cites W2314103148 @default.
• W4283277583 cites W2324227496 @default.
• W4283277583 cites W2325521630 @default.
• W4283277583 cites W2327093149 @default.
• W4283277583 cites W2331129062 @default.
• W4283277583 cites W2331636866 @default.
• W4283277583 cites W2332164006 @default.
• W4283277583 cites W2334529210 @default.
• W4283277583 cites W2334703837 @default.
• W4283277583 cites W2395336894 @default.
• W4283277583 cites W2398974167 @default.
• W4283277583 cites W240928859 @default.
• W4283277583 cites W2433019965 @default.
• W4283277583 cites W2470074591 @default.
• W4283277583 cites W2520000831 @default.
• W4283277583 cites W2549369196 @default.
• W4283277583 cites W2552273631 @default.
• W4283277583 cites W2558874365 @default.
• W4283277583 cites W2586186075 @default.
• W4283277583 cites W2607315915 @default.

• next