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- W4283316124 abstract "Four aluminum, zinc, and aluminum/zinc heterometallic complexes 1–4 stabilized by o ‐phenylenediamine bridged poly (phenolato) ligands were synthesized and characterized. It was found that the reaction sequence has significant influence on the formation of the Al‐Zn heterometallic complex AlZnL 1 Me ( 4 ), which was prepared through successive complexation of poly (phenol) with ZnEt 2 and AlMe 3 . The catalytic behaviors of complexes 1–4 for the ring‐opening polymerization of cyclohexene oxide (CHO) were investigated, and the heterometallic complex 4 showed significantly enhanced activity (TOF up to 410 min −1 ). Kinetic study was conducted; the activation energy ( E a ) for formation of PCHO using 4 was determined to be 58.0 ± 6.5 kJ mol −1 ." @default.
- W4283316124 created "2022-06-24" @default.
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- W4283316124 date "2022-07-04" @default.
- W4283316124 modified "2023-09-26" @default.
- W4283316124 title "Synthesis and characterization of Al (III)‐Zn (II) heterometallic complex and the application in ring‐opening polymerization of cyclohexene oxide" @default.
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- W4283316124 doi "https://doi.org/10.1002/aoc.6796" @default.
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