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- W4283380147 abstract "Using renewable feedstocks to access highly functionalized molecules in a concise manner is a promising approach to sustainable syntheses. Previous studies used malononitrile to convert simple sugars to polyhydroxylalkyl aminofurans in the presence of various catalysts. Herein, a chemodivergent method is disclosed for the reaction of the same unprotected sugars with malononitrile to instead form bicyclic 2,3-dihydrofuran products in yields up to 85% with good regioselectivities. Kinetic, NMR, and computational studies support a proposed mechanism for the formation of dihydrofuran products. By employing a mild set of reaction conditions (aqueous solvent, at room temperature, in under 4 h) and a recyclable heterogeneous MgO catalyst, this method serves as a powerful tool for carbohydrate upcycling that offers useful and interesting nonaromatic products." @default.
- W4283380147 created "2022-06-25" @default.
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- W4283380147 date "2022-04-25" @default.
- W4283380147 modified "2023-09-25" @default.
- W4283380147 title "Selective Conversion of Malononitrile and Unprotected Carbohydrates to Bicyclic Polyhydroxyalkyl Dihydrofurans Using Magnesium Oxide as a Recyclable Catalyst" @default.
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- W4283380147 doi "https://doi.org/10.1021/acssuschemeng.2c00723" @default.
- W4283380147 hasPublicationYear "2022" @default.
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