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- W4283387127 abstract "A TEMPO-promoted method was developed for the synthesis of symmetric bis-N-Mannich bases via sequential activation of two α,α'-amino C(sp3)-H bonds of N,N-dimethylanilines under mild conditions. This methodology was further extended for monoimidation of α-amino-functionalized methylanilines to give unsymmetric N-Mannich bases in good to high yields. Several control experiments were performed, and the coupling reaction outcomes indicated that the oxoammonium (TEMPO+) species is involved in the reaction." @default.
- W4283387127 created "2022-06-25" @default.
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- W4283387127 date "2022-06-24" @default.
- W4283387127 modified "2023-09-27" @default.
- W4283387127 title "TEMPO-Promoted Mono- and Bisimidation of Tertiary Anilines: Synthesis of Symmetric and Unsymmetric <i>N</i>-Mannich Bases" @default.
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- W4283387127 doi "https://doi.org/10.1021/acs.joc.2c00700" @default.
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