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• W4283445633 endingPage "494" @default.
• W4283445633 startingPage "485" @default.
• W4283445633 abstract "The self-assembly in the mixtures of (ethoxy)(oxo)(5,10,15,20-(4-tert-butylphenyl)-porphinato)molybdenum(V) (O=Mo(OEt)T[Formula: see text]BuPP) with pyridine and 1-N-methyl-2-(pyridin-4-yl)-3,4-fullero[60]pyrrolidine (PyF) in toluene was quantitatively studied using the UV-vis, IR, 1 H NMR, mass spectrometry methods, chemical thermodynamics/kinetics, and X-ray phase analysis. The axial bonding of the pyridine molecule with O=Mo(OEt)T[Formula: see text]BuPP proceeds as two step equilibriums with the equilibrium constants [Formula: see text] 2.58 × 10 2 L/mol and [Formula: see text] 1.48 × 10 2 L/mol. The relative optical response to the presence of pyridine corresponding to the first and second equilibrium [Formula: see text] was found to be aqual 0.23 and 0.19. The novel fluorescence quenching donor-acceptor system, O=Mo(PyF) 2 T[Formula: see text]BuPP][Formula: see text]OEt[Formula: see text], together with its full characterization are represented. The results obtained will be useful in the development of sensors for organic bases and photoactive molecular materials for optoelectronics." @default.
• W4283445633 created "2022-06-26" @default.
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• W4283445633 date "2022-06-01" @default.
• W4283445633 modified "2023-09-27" @default.
• W4283445633 title "The formation kinetics, the chemical structure and the application prospects of the (ethoxy)(oxo)(5,10,15,20-(4-tert-butylphenyl)porphinato)molybdenum(V)coordination complexes with pyridine/pyridine bearing 1-N-methyl-3,4-fullero[60]pyrrolidine" @default.
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• W4283445633 doi "https://doi.org/10.1142/s1088424622500365" @default.
• W4283445633 hasPublicationYear "2022" @default.
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