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- W4283511655 abstract "Sulfur compounds in transportation fuels have been a major concern for environmental researchers due to the production of their obnoxious oxides. This work reports the preparation of Fe2O3, NiO2, and ZnO promoted Montmorillonite (MMT) catalyzed O2/CH3COOH oxidation system for the elimination of dibenzothiophene (DBT) from transportation fuels oils. The as-synthesized catalysts were characterized via FTIR, EDX SEM, and XRD techniques which suggested intriguing surface properties conducive to the removal of DBT molecules. Desulfurization activity experiments showed that Fe2O3/MMT-O2/CH3COOH catalyst-oxidant system decreased the sulfur content (from a model solution) from 500 to 22.9 ppm in 60 min at 60 °C. Under the optimized conditions, the sulfur levels from commercial gasoline, diesel and kerosene oil were decreased from 25.3 to 11.7 mg/L, 3800.53 to 1467.7 mg/L and 3296.6 2450 mg/L, respectively. The spent catalysts were also characterized in detail which justified the catalytic activity of different catalysts. Accrediting its environmental benignity, cost-effectiveness, and ease of preparation, this study provides important reference information for the industrial-scale desulfurization of transportation oils." @default.
- W4283511655 created "2022-06-27" @default.
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- W4283511655 date "2022-06-25" @default.
- W4283511655 modified "2023-09-30" @default.
- W4283511655 title "Preparation of Fe<sub>2</sub>O<sub>3</sub>, NiO<sub>2</sub>, and ZnO supported montmorillonite clay for oxidative desulfurization of transportation fuels in O<sub>2</sub>/CH<sub>3</sub>COOH oxidation system" @default.
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- W4283511655 doi "https://doi.org/10.1080/10916466.2022.2092503" @default.
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