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• W4283574186 startingPage "3238" @default.
• W4283574186 abstract "Developing flexible polyurethane foam (FPUF) with good anti-ignition and self-extinguishing performance is the fundamental way to prevent fire hazards in application. A binary composite system containing ammonium hypophosphite (NHP) and expandable graphite (EG) was applied to prepare flame-retardant FPUF. The co-action of NHP and EG exhibited high-efficiency synergistic effect in improving the anti-ignition, self-extinguishing, and carbonization performance of FPUF. The analysis of micromorphology, element retention and chemical structure character on charring residue, reveals the physical–chemical synergistic carbonization mechanism of NHP/EG composite. The real-time tracing on thermal-decomposition volatiles, discloses the behaviors of NHP/EG composite in suppressing volatile fuel supply and toxic fume production. With an addition of 11 wt.% NHP and 7 wt.% EG, 11NHP/7EG achieved a limited oxygen index value of 30.3%, passed horizontal burning class HF-1, and retained 55.6 wt.% charring residue. The peak of heat release rate and total heat release of 11NHP/7EG were both reduced by more than 50%, compared with that of pristine FPUF. The synergistic flame-retardant mechanism of NHP/EG composite provides a valuable reference for high-performance flame-retardant FPUF manufacturing." @default.
• W4283574186 created "2022-06-28" @default.
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• W4283574186 date "2022-06-26" @default.
• W4283574186 modified "2023-10-15" @default.
• W4283574186 title "Carbonization‐dominated synergistic behaviors of ammonium hypophosphite/ <scp>EG</scp> composite in improving flame retardancy of flexible polyurethane foam" @default.
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• W4283574186 doi "https://doi.org/10.1002/pat.5775" @default.
• W4283574186 hasPublicationYear "2022" @default.
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