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- W4283578633 abstract "Here, a series of Mn-Ce binary oxides loaded monolith catalysts, with the support consisting of Na-Al2O3 grown on Al mesh obtained by steam vapor treating, were prepared to attain efficient toluene destruction. On increasing CeO2 loading, the toluene conversion over prepared catalysts shows an exponential rise, with Mn-4Ce@Na-Al2O3@Al monolithic catalyst exhibiting the optimal performance, over which 90% of toluene can be decomposed at 239 °C with oxidation rate over 5.57 × 10−7 mol·g−1·s−1, obviously higher than those over 4Ce/Na-Al2O3@Al (239 °C; 0.99 × 10−7 mol·g−1·s−1) and Mn/Na-Al2O3@Al (291 °C; 4.12 × 10−7 mol·g−1·s−1). H2-TPR and XPS results reveal that the superior redox ability and the formation of MnCeOx solid solution are favorable for toluene abatement. Oxygen vacancies form easily on the surface of Ce modified samples, resulting in superior oxygen and toluene adsorption ability, as demonstrated by DFT theoretical calculation. Besides, the pathways of toluene oxidation over Mn-4Ce@Na-Al2O3@Al catalyst were identified by using the in situ DRIFTS, and the key intermediates of toluene oxidation reaction are determined to be benzoyl, benzaldehyde, and benzoate." @default.
- W4283578633 created "2022-06-28" @default.
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- W4283578633 date "2022-10-01" @default.
- W4283578633 modified "2023-10-18" @default.
- W4283578633 title "Dramatically promoted toluene destruction over Mn@Na-Al2O3@Al monolithic catalysts by Ce incorporation: Oxygen vacancy construction and reaction mechanism" @default.
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- W4283578633 doi "https://doi.org/10.1016/j.fuel.2022.125051" @default.
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