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- W4283660123 abstract "Herein, we report the mechanochemical synthesis of a new aryl sulfonium polyoxometalate (ASPOM), (FPDS)3[PMo12O40] (FPMA) (FPDS = (4-formylphenyl)dimethylsulfonium)) and the single-crystal X-ray analyses of its one-electron reduced species (FPDS)4[PMo12O40]. The Hirshfeld surface analysis has been performed to quantify the non-covalent interactions in the hybrid. The hybrid is also shown to be photochromic in nature, following a pseudo-first-order rate law with a photo coloration half-life of 18.5 min." @default.
- W4283660123 created "2022-06-29" @default.
- W4283660123 creator A5080431860 @default.
- W4283660123 date "2022-11-01" @default.
- W4283660123 modified "2023-10-18" @default.
- W4283660123 title "A New Aryl Sulfonium Polyoxomolybate with One-Electron Reduced Keggin Cluster: Crystal Structure, Hirshfeld Analysis, and Photochromic Activity" @default.
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- W4283660123 doi "https://doi.org/10.1016/j.molstruc.2022.133603" @default.
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