Matches in SemOpenAlex for { <https://semopenalex.org/work/W4283702967> ?p ?o ?g. }
- W4283702967 abstract "Abstract The use of alkylarenes as nucleophile precursors in benzylic addition is challenging because the benzylic hydrogen atoms of these compounds are inert to deprotonation. Herein, we report Rh‐catalyzed benzylic addition of alkylarenes to Michael acceptors for the formation of C(sp 3 )−C(sp 3 ) bonds. The catalyst is proposed to activate the aromatic ring via η 6 ‐coordination, dramatically facilitating deprotonation of the unactivated benzylic C−H bond and addition of the resulting carbanion to the α,β‐unsaturated double bond in the absence of bases. Notably, this byproduct‐free method provides an access to all‐carbon quaternary centers through the development of ligands." @default.
- W4283702967 created "2022-06-30" @default.
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- W4283702967 creator A5057841029 @default.
- W4283702967 creator A5068712825 @default.
- W4283702967 date "2022-07-19" @default.
- W4283702967 modified "2023-10-17" @default.
- W4283702967 title "Rhodium‐Catalyzed Benzylic Addition Reactions of Alkylarenes to Michael Acceptors" @default.
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- W4283702967 doi "https://doi.org/10.1002/anie.202207917" @default.
- W4283702967 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35767354" @default.
- W4283702967 hasPublicationYear "2022" @default.
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