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• W4283716687 abstract "An efficient methodology has been developed for the synthesis of both di- and trisubstituted thiazol-2(3H)-ones from N-propargylamines and silver(I) trifluoromethanethiolate (AgSCF3) in good yields. The reaction proceeds via [3,3]-sigmatropic rearrangement/5-exo-dig cyclization of N-propargylamines. The starting material can be easily prepared from the A3-coupling reaction of amines, aldehydes, and alkynes. The methodology can be extended for the synthesis of thiozole-2(3H)-thione derivatives, and photophysical properties have been studied for some synthesized compounds." @default.
• W4283716687 created "2022-07-01" @default.
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• W4283716687 date "2022-06-30" @default.
• W4283716687 modified "2023-09-30" @default.
• W4283716687 title "Synthesis of Thiazole-2(3<i>H</i>)-ones via [3,3]-Sigmatropic Rearrangement/5-<i>exo</i>-dig Cyclization of <i>N</i>-Propargylamines" @default.
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• W4283716687 doi "https://doi.org/10.1021/acs.joc.2c00991" @default.
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