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- W4283720008 abstract "The [Cr(NO)(MeCN)5]2+ synthon reacts with the Ni(N2S2) metallodithiolate ligand to yield co-crystallized products from which crystals suitable for SC-XRD could be extracted. The major product, {trans-(MeCN)Cr(NO)[Ni(N2S2)]2}2+, abbreviated [Cr(NO)Ni2]2+, is a symmetrical butterfly with upswept Ni(N2S2) wings flanking the trans-Cr(NO)(MeCN) backbone and designated {Cr(NO)}5 in Enemark-Feltham notation (Feltham and Enemark, 1981). The minor product, {Cr[Ni(N2S2)]3}3+, abbreviated [CrNi3]3+, is a pinwheel-type structure analogous to [RhNi3]3+, and both are comparable to tris-bipyridyl analogues." @default.
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- W4283720008 date "2022-09-01" @default.
- W4283720008 modified "2023-10-18" @default.
- W4283720008 title "Structural analysis of heteropolymetallic complexes: A chiral pinwheel {Cr[Ni(N2S2)]3}3+ and the {trans-(MeCN)Cr(NO)[Ni(N2S2)]2}2+ basket" @default.
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- W4283720008 doi "https://doi.org/10.1016/j.poly.2022.116018" @default.
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