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- W4283722809 abstract "The strong light–matter coupling regime, in which excitations of materials hybridize with excitations of confined light modes into polaritons, holds great promise in various areas of science and technology. A key aspect for all applications of polaritonic chemistry is the relaxation into the lower polaritonic states. Polariton relaxation is speculated to involve two separate processes: vibrationally assisted scattering (VAS) and radiative pumping (RP), but the driving forces underlying these two mechanisms are not fully understood. To provide mechanistic insights, we performed multiscale molecular dynamics simulations of tetracene molecules strongly coupled to the confined light modes of an optical cavity. The results suggest that both mechanisms are driven by the same molecular vibrations that induce relaxation through nonadiabatic coupling between dark states and polaritonic states. Identifying these vibrational modes provides a rationale for enhanced relaxation into the lower polariton when the cavity detuning is resonant with specific vibrational transitions." @default.
- W4283722809 created "2022-07-01" @default.
- W4283722809 creator A5011483649 @default.
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- W4283722809 creator A5039957211 @default.
- W4283722809 creator A5051035375 @default.
- W4283722809 creator A5070936021 @default.
- W4283722809 date "2022-06-30" @default.
- W4283722809 modified "2023-09-27" @default.
- W4283722809 title "Identifying Vibrations that Control Non-adiabatic Relaxation of Polaritons in Strongly Coupled Molecule–Cavity Systems" @default.
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- W4283722809 doi "https://doi.org/10.1021/acs.jpclett.2c00826" @default.
- W4283722809 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35771724" @default.
- W4283722809 hasPublicationYear "2022" @default.
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