FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4283747356> ?p ?o ?g. }

• W4283747356 endingPage "23590" @default.
• W4283747356 startingPage "23576" @default.
• W4283747356 abstract "Low-cost mesoporous silicas of the SBA-15 family were prepared, aimed for removal of a broad spectrum of both cationic and anionic forms of hazardous metal pollutants (Cr(III, VI), Mn(II, VII), Pb(II), Cd(II), and Cu(II)) from environmental water. Series of mono- and bifunctional materials with immobilized ethylenediaminetriacetic acid (EDTA), primary amine (NH2), and quaternary ammonium (QAS) groups were prepared in a cost-efficient one-step synthesis using two silica sources, low-cost sodium metasilicate (Na2SiO3 9H2O) and the conventional source─tetraethylorthosilicate (TEOS). The functionalized SBA-15 samples obtained from both silica sources were highly ordered, as evidenced by TEM and SAXS data. All obtained materials were mesoporous with high surface area values of up to 745 m2/g, pore volumes from 0.99 to 1.44 cm3/g, and narrow pore distributions near 7 nm. The adsorption affinity of the EDTA-functionalized samples followed the common order Pb(II)> Cd(II)> Cu(II)> Cr(III)> Mn(II), which could be explained based on the Pearson theory. The highest adsorption capacities were observed for samples functionalized by EDTA groups using TEOS for synthesis (TEOS/EDTA): 195.6 mg/g for Pb(II), 111.2 mg/g for Cd(II), 58.7 mg/g for Cu(II), 57.7 mg/g for Cr(III), and 49.4 mg/g for Mn(II). Moreover, organic matter (humic acid up to 10 mg/L) and inorganic (Na(I), K(I), Mg(II), Ca(II), etc) macrocomponents present in environmental water had almost negligible effect on the removal of these cations. The NaSi/EDTA/NH2 sample revealed a better selectivity compared to the NaSi/NH2 sample towards such species as Cr(III), Mn(II), Cd(II), and Cu(II). The chromate-ions uptake at pH 7.5 by the TEOS/QAS sample turned practically unaffected by the presence of doubly charged anions (CO32–, SO42–). The content of functional groups on the surface of MS decreased only slightly (∼1–5%) after several regeneration cycles. The complete desorption of all heavy metal ions can be achieved using 1 mol/L EDTA solution. Reusability tests demonstrated the complete stability of the adsorbent for at least five to six consecutive adsorption/desorption cycles with no decrease in its adsorption characteristics compared to those obtained by 0.05 mol/L HNO3 treatments. The synthesized mesoporous materials were evaluated for removal of the heavy metal ions from drinking and different natural water samples, proving their potential as sustainable, effective, and cost-efficient adsorbents." @default.
• W4283747356 created "2022-07-02" @default.
• W4283747356 creator A5018139763 @default.
• W4283747356 creator A5021061957 @default.
• W4283747356 creator A5036513853 @default.
• W4283747356 creator A5088796006 @default.
• W4283747356 date "2022-07-01" @default.
• W4283747356 modified "2023-10-17" @default.
• W4283747356 title "In situ Functionalized Mesoporous Silicas for Sustainable Remediation Strategies in Removal of Inorganic Pollutants from Contaminated Environmental Water" @default.
• W4283747356 cites W1510722917 @default.
• W4283747356 cites W1528268897 @default.
• W4283747356 cites W1971877735 @default.
• W4283747356 cites W1987803802 @default.
• W4283747356 cites W1988745485 @default.
• W4283747356 cites W1995275534 @default.
• W4283747356 cites W2005877813 @default.
• W4283747356 cites W2007235051 @default.
• W4283747356 cites W2011254969 @default.
• W4283747356 cites W2014839814 @default.
• W4283747356 cites W2030674380 @default.
• W4283747356 cites W2033281119 @default.
• W4283747356 cites W2037678953 @default.
• W4283747356 cites W2039025571 @default.
• W4283747356 cites W2044840163 @default.
• W4283747356 cites W2046430541 @default.
• W4283747356 cites W2046594437 @default.
• W4283747356 cites W2059359906 @default.
• W4283747356 cites W2081288174 @default.
• W4283747356 cites W2089303208 @default.
• W4283747356 cites W2092410844 @default.
• W4283747356 cites W2093687707 @default.
• W4283747356 cites W2112017750 @default.
• W4283747356 cites W2119862261 @default.
• W4283747356 cites W2124592910 @default.
• W4283747356 cites W2143438291 @default.
• W4283747356 cites W2144283342 @default.
• W4283747356 cites W2255786456 @default.
• W4283747356 cites W2291637320 @default.
• W4283747356 cites W2312199777 @default.
• W4283747356 cites W2560108397 @default.
• W4283747356 cites W2597969905 @default.
• W4283747356 cites W2734417222 @default.
• W4283747356 cites W2770312871 @default.
• W4283747356 cites W2807348562 @default.
• W4283747356 cites W2883150550 @default.
• W4283747356 cites W2909574007 @default.
• W4283747356 cites W2925061258 @default.
• W4283747356 cites W2954272742 @default.
• W4283747356 cites W2977924735 @default.
• W4283747356 cites W2988595720 @default.
• W4283747356 cites W3005305856 @default.
• W4283747356 cites W3011324402 @default.
• W4283747356 cites W3029913968 @default.
• W4283747356 cites W3034100362 @default.
• W4283747356 cites W3036620931 @default.
• W4283747356 cites W3044534638 @default.
• W4283747356 cites W3077769243 @default.
• W4283747356 cites W3092633905 @default.
• W4283747356 cites W3106384017 @default.
• W4283747356 cites W3128608678 @default.
• W4283747356 cites W4234562034 @default.
• W4283747356 cites W4243616280 @default.
• W4283747356 cites W4285751521 @default.
• W4283747356 doi "https://doi.org/10.1021/acsomega.2c02151" @default.
• W4283747356 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35847252" @default.
• W4283747356 hasPublicationYear "2022" @default.
• W4283747356 type Work @default.
• W4283747356 citedByCount "5" @default.
• W4283747356 countsByYear W42837473562022 @default.
• W4283747356 countsByYear W42837473562023 @default.
• W4283747356 crossrefType "journal-article" @default.
• W4283747356 hasAuthorship W4283747356A5018139763 @default.
• W4283747356 hasAuthorship W4283747356A5021061957 @default.
• W4283747356 hasAuthorship W4283747356A5036513853 @default.
• W4283747356 hasAuthorship W4283747356A5088796006 @default.
• W4283747356 hasBestOaLocation W42837473562 @default.
• W4283747356 hasConcept C112570922 @default.
• W4283747356 hasConcept C13965031 @default.
• W4283747356 hasConcept C150394285 @default.
• W4283747356 hasConcept C161790260 @default.
• W4283747356 hasConcept C178790620 @default.
• W4283747356 hasConcept C179104552 @default.
• W4283747356 hasConcept C183882617 @default.
• W4283747356 hasConcept C185592680 @default.
• W4283747356 hasConcept C18903297 @default.
• W4283747356 hasConcept C2777496208 @default.
• W4283747356 hasConcept C2779870022 @default.
• W4283747356 hasConcept C2780443040 @default.
• W4283747356 hasConcept C2780560099 @default.
• W4283747356 hasConcept C2780965034 @default.
• W4283747356 hasConcept C522964758 @default.
• W4283747356 hasConcept C82776694 @default.
• W4283747356 hasConcept C86803240 @default.
• W4283747356 hasConceptScore W4283747356C112570922 @default.
• W4283747356 hasConceptScore W4283747356C13965031 @default.
• W4283747356 hasConceptScore W4283747356C150394285 @default.
• W4283747356 hasConceptScore W4283747356C161790260 @default.
• W4283747356 hasConceptScore W4283747356C178790620 @default.

• next