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• W4283751454 endingPage "140" @default.
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• W4283751454 abstract "Lyotropic liquid crystals (LLCs) produced by the self-assembly of surfactant in water represent an important class of highly ordered soft materials that have a wide range of applications. This study investigates the LLCs formed by a zwitterionic surfactant (tetradecyldimethylaminoxide, C14DMAO) in water. The organization of C14DMAO within the LLCs was determined based on a detailed analysis of small-angle X-ray scattering measurements and polarized microscopy observations of a typical sample. Additional to the singe-phase region, which has a hexagonal organization, several two-phase regions were observed, exhibiting the coexistence of hexagonal/cubic, cubic/lamellar, and hexagonal/lamellar phases. The phase behavior showed an obvious dependence on temperature, with more pronounced two-phase regions at lower temperatures. Using the LLCs as a matrix, Au nanospheres, nanoellipsoids, and nanorods were prepared without requiring additional reducing reagents. These three- and one-dimensional Au nanomaterials could be converted to two-dimensional plates via the introduction of a small amount of cationic surfactant to the LLCs, such as cetyltrimethylammonium bromide (CTAB) and 1-hexadecyl-3-methylimidazolium bromide ([C16MIm]B), which showed pronounced surface-enhanced Raman scattering activity towards solid rhodamine. The LLCs loaded with CTAB (or [C16MIm]B) and HAuCl4 exhibited slightly different structures and mechanical strength from the original LLCs, thereby forming a new class of highly crowded colloidal materials." @default.
• W4283751454 created "2022-07-02" @default.
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• W4283751454 date "2023-04-01" @default.
• W4283751454 modified "2023-09-25" @default.
• W4283751454 title "Lyotropic liquid crystals of tetradecyldimethylaminoxide in water and the in situ formation of gold nanomaterials" @default.
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• W4283751454 doi "https://doi.org/10.1016/j.chphma.2022.06.001" @default.
• W4283751454 hasPublicationYear "2023" @default.
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