FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4283756721> ?p ?o ?g. }

• W4283756721 endingPage "2201359" @default.
• W4283756721 startingPage "2201359" @default.
• W4283756721 abstract "In this work, electrocatalytic upgrade of n-valeraldehyde to octane with higher activity and selectivity is achieved over Au single-atom catalysts (SACs)–NiMn2O4 spinel synergetic composites. Experiments combined with density functional theory calculation collaboratively demonstrate that Au single-atoms occupy surface Ni2+ vacancies of NiMn2O4, which play a dominant role in n-valeraldehyde selective oxidation. A detailed investigation reveals that the initial n-valeraldehyde molecule preferentially adsorbs on the Mn tetrahedral site of NiMn2O4 spinel synergetic structures, and the subsequent n-valeraldehyde molecule easily adsorbs on the Ni site. Specifically, Au single-atom surficial derivation over spinel lowers the adsorption energy (Eads) of the initial n-valeraldehyde molecule, which will facilitate its adsorption on the Mn site of Au SACs–NiMn2O4. Furthermore, the single-atom Au surficial derivation not only alters the electronic structure of Au SACs–NiMn2O4 but also lower the Eads of subsequent n-valeraldehyde molecule. Hence, the subsequent n-valeraldehyde molecules prefer adsorption on Au sites rather than Ni sites, and the process of two alkyl radicals originating from Mn–C4H9 and Au–C4H9 dimerization into an octane is accordingly accelerated. This work will provide an avenue for the rational design of SACs and supply a vital mechanism for understanding the electrocatalytic upgrade of n-valeraldehyde to octane." @default.
• W4283756721 created "2022-07-02" @default.
• W4283756721 creator A5003635160 @default.
• W4283756721 creator A5011145748 @default.
• W4283756721 creator A5016637706 @default.
• W4283756721 creator A5030022565 @default.
• W4283756721 creator A5051441576 @default.
• W4283756721 creator A5056165846 @default.
• W4283756721 date "2022-06-29" @default.
• W4283756721 modified "2023-09-25" @default.
• W4283756721 title "Highly Efficient Electrocatalytic Upgrade of <i>n</i> ‐Valeraldehyde to Octane over Au SACs–NiMn ₂ O ₄ Spinel Synergetic Composites" @default.
• W4283756721 cites W2015194545 @default.
• W4283756721 cites W2036103055 @default.
• W4283756721 cites W2046931018 @default.
• W4283756721 cites W2128601835 @default.
• W4283756721 cites W2135160534 @default.
• W4283756721 cites W2139920822 @default.
• W4283756721 cites W2281185144 @default.
• W4283756721 cites W2282896142 @default.
• W4283756721 cites W2314274336 @default.
• W4283756721 cites W2438176715 @default.
• W4283756721 cites W2519218628 @default.
• W4283756721 cites W2550380597 @default.
• W4283756721 cites W2607316969 @default.
• W4283756721 cites W2612383933 @default.
• W4283756721 cites W2614326779 @default.
• W4283756721 cites W2783891392 @default.
• W4283756721 cites W2794172956 @default.
• W4283756721 cites W2801231312 @default.
• W4283756721 cites W2808561284 @default.
• W4283756721 cites W2887691089 @default.
• W4283756721 cites W2895459266 @default.
• W4283756721 cites W2897433645 @default.
• W4283756721 cites W2900008062 @default.
• W4283756721 cites W2909740062 @default.
• W4283756721 cites W2944909117 @default.
• W4283756721 cites W2947521638 @default.
• W4283756721 cites W2951443955 @default.
• W4283756721 cites W2969095743 @default.
• W4283756721 cites W2970759029 @default.
• W4283756721 cites W2974609736 @default.
• W4283756721 cites W2975512707 @default.
• W4283756721 cites W2977207800 @default.
• W4283756721 cites W2979399439 @default.
• W4283756721 cites W2984236507 @default.
• W4283756721 cites W2986489125 @default.
• W4283756721 cites W2987768094 @default.
• W4283756721 cites W3013305684 @default.
• W4283756721 cites W3022892760 @default.
• W4283756721 cites W3043408787 @default.
• W4283756721 cites W3045914842 @default.
• W4283756721 cites W3084028693 @default.
• W4283756721 cites W3093553110 @default.
• W4283756721 cites W3093707113 @default.
• W4283756721 cites W3113867019 @default.
• W4283756721 cites W3119227933 @default.
• W4283756721 cites W3119379949 @default.
• W4283756721 cites W3130178323 @default.
• W4283756721 cites W3156836331 @default.
• W4283756721 cites W3186970166 @default.
• W4283756721 cites W3193144183 @default.
• W4283756721 cites W3196372635 @default.
• W4283756721 cites W3201441496 @default.
• W4283756721 cites W4235131310 @default.
• W4283756721 doi "https://doi.org/10.1002/smll.202201359" @default.
• W4283756721 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35768281" @default.
• W4283756721 hasPublicationYear "2022" @default.
• W4283756721 type Work @default.
• W4283756721 citedByCount "2" @default.
• W4283756721 countsByYear W42837567212023 @default.
• W4283756721 crossrefType "journal-article" @default.
• W4283756721 hasAuthorship W4283756721A5003635160 @default.
• W4283756721 hasAuthorship W4283756721A5011145748 @default.
• W4283756721 hasAuthorship W4283756721A5016637706 @default.
• W4283756721 hasAuthorship W4283756721A5030022565 @default.
• W4283756721 hasAuthorship W4283756721A5051441576 @default.
• W4283756721 hasAuthorship W4283756721A5056165846 @default.
• W4283756721 hasConcept C111919701 @default.
• W4283756721 hasConcept C147789679 @default.
• W4283756721 hasConcept C149635348 @default.
• W4283756721 hasConcept C150394285 @default.
• W4283756721 hasConcept C178790620 @default.
• W4283756721 hasConcept C185592680 @default.
• W4283756721 hasConcept C191897082 @default.
• W4283756721 hasConcept C192562407 @default.
• W4283756721 hasConcept C2776230739 @default.
• W4283756721 hasConcept C2776624427 @default.
• W4283756721 hasConcept C2780615140 @default.
• W4283756721 hasConcept C32909587 @default.
• W4283756721 hasConcept C41008148 @default.
• W4283756721 hasConcept C58312451 @default.
• W4283756721 hasConceptScore W4283756721C111919701 @default.
• W4283756721 hasConceptScore W4283756721C147789679 @default.
• W4283756721 hasConceptScore W4283756721C149635348 @default.
• W4283756721 hasConceptScore W4283756721C150394285 @default.
• W4283756721 hasConceptScore W4283756721C178790620 @default.
• W4283756721 hasConceptScore W4283756721C185592680 @default.
• W4283756721 hasConceptScore W4283756721C191897082 @default.

• next