FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4283768088> ?p ?o ?g. }

• W4283768088 endingPage "101005" @default.
• W4283768088 startingPage "101005" @default.
• W4283768088 abstract "High-performance catalytic reactions and easy-to-recycle property of noble metal catalysts are desirable in chemical productions, and a suitably combined pathway of both homogeneous and heterogeneous catalysis is promising in this regard. Herein, a novel thermoresponsive nanocomposite catalyst is designed through the “grafting-from” reaction of the thermoresponsive motifs and the “self-reduction” reaction of the noble metal ions at transition metal carbides (MXene) surface. The prepared catalyst with Au nanoparticles as active catalytic species, poly(N-isopropylacrylamide) as thermoresponsive switch, and MXene as catalyst-carrying substrate has a superior thermoresponsiveness of phase transitions (i.e., between suspended and aggregated states in aqueous conditions), which facilitates to the control of heterogeneous catalysis by surrounding temperatures. A high turnover frequency of up to 11.73 min−1 can be achieved for the 4-nitrophenol reduction at room temperature. Notably, the reaction can be easily terminated at elevated temperatures (e.g., 40 °C), with the catalysts being separated and recovered (i.e., by precipitation) in the meantime. The nanocomposite therefore combines both merits of the homogeneous catalysts (e.g., high-performance) and the heterogeneous catalysts (i.e., easy-to-recycle) and display tunable catalytic activity at low/high temperatures. The design principle and the smart ON/OFF control of the catalytic process demonstrated in this work are promising for industrial applications." @default.
• W4283768088 created "2022-07-03" @default.
• W4283768088 creator A5004171503 @default.
• W4283768088 creator A5004917251 @default.
• W4283768088 creator A5024392684 @default.
• W4283768088 creator A5030963316 @default.
• W4283768088 creator A5031249453 @default.
• W4283768088 creator A5043225065 @default.
• W4283768088 creator A5066012333 @default.
• W4283768088 creator A5067018386 @default.
• W4283768088 creator A5076138286 @default.
• W4283768088 date "2022-12-01" @default.
• W4283768088 modified "2023-10-16" @default.
• W4283768088 title "Thermoresponsive MXene nanocomposite catalyst with high activity and thermosensitivity for controlled heterogeneous catalysis" @default.
• W4283768088 cites W2038020702 @default.
• W4283768088 cites W2266564964 @default.
• W4283768088 cites W2566202566 @default.
• W4283768088 cites W2779291366 @default.
• W4283768088 cites W2803808473 @default.
• W4283768088 cites W2914355291 @default.
• W4283768088 cites W2933408092 @default.
• W4283768088 cites W2940391442 @default.
• W4283768088 cites W2941627450 @default.
• W4283768088 cites W2955981865 @default.
• W4283768088 cites W2966822626 @default.
• W4283768088 cites W2973916571 @default.
• W4283768088 cites W2974450106 @default.
• W4283768088 cites W2977573947 @default.
• W4283768088 cites W2980828480 @default.
• W4283768088 cites W2981574400 @default.
• W4283768088 cites W2981719534 @default.
• W4283768088 cites W2987000594 @default.
• W4283768088 cites W2993033529 @default.
• W4283768088 cites W3005549070 @default.
• W4283768088 cites W3014335985 @default.
• W4283768088 cites W3025508996 @default.
• W4283768088 cites W3026710733 @default.
• W4283768088 cites W3033402837 @default.
• W4283768088 cites W3033667680 @default.
• W4283768088 cites W3041286934 @default.
• W4283768088 cites W3043115209 @default.
• W4283768088 cites W3048606076 @default.
• W4283768088 cites W3048781706 @default.
• W4283768088 cites W3050779326 @default.
• W4283768088 cites W3062189215 @default.
• W4283768088 cites W3096027022 @default.
• W4283768088 cites W3101793878 @default.
• W4283768088 cites W3107339266 @default.
• W4283768088 cites W3108252687 @default.
• W4283768088 cites W3108688908 @default.
• W4283768088 cites W3120524341 @default.
• W4283768088 cites W3126322909 @default.
• W4283768088 cites W3132339502 @default.
• W4283768088 cites W3136784665 @default.
• W4283768088 cites W3160812560 @default.
• W4283768088 cites W3164839497 @default.
• W4283768088 cites W3170049773 @default.
• W4283768088 cites W3187093992 @default.
• W4283768088 cites W3198264860 @default.
• W4283768088 cites W3200092575 @default.
• W4283768088 cites W3202336676 @default.
• W4283768088 cites W3204326214 @default.
• W4283768088 doi "https://doi.org/10.1016/j.mtchem.2022.101005" @default.
• W4283768088 hasPublicationYear "2022" @default.
• W4283768088 type Work @default.
• W4283768088 citedByCount "0" @default.
• W4283768088 crossrefType "journal-article" @default.
• W4283768088 hasAuthorship W4283768088A5004171503 @default.
• W4283768088 hasAuthorship W4283768088A5004917251 @default.
• W4283768088 hasAuthorship W4283768088A5024392684 @default.
• W4283768088 hasAuthorship W4283768088A5030963316 @default.
• W4283768088 hasAuthorship W4283768088A5031249453 @default.
• W4283768088 hasAuthorship W4283768088A5043225065 @default.
• W4283768088 hasAuthorship W4283768088A5066012333 @default.
• W4283768088 hasAuthorship W4283768088A5067018386 @default.
• W4283768088 hasAuthorship W4283768088A5076138286 @default.
• W4283768088 hasConcept C106773901 @default.
• W4283768088 hasConcept C127413603 @default.
• W4283768088 hasConcept C155672457 @default.
• W4283768088 hasConcept C161790260 @default.
• W4283768088 hasConcept C171250308 @default.
• W4283768088 hasConcept C175583648 @default.
• W4283768088 hasConcept C178790620 @default.
• W4283768088 hasConcept C185592680 @default.
• W4283768088 hasConcept C192562407 @default.
• W4283768088 hasConcept C2775871042 @default.
• W4283768088 hasConcept C42360764 @default.
• W4283768088 hasConcept C92880739 @default.
• W4283768088 hasConceptScore W4283768088C106773901 @default.
• W4283768088 hasConceptScore W4283768088C127413603 @default.
• W4283768088 hasConceptScore W4283768088C155672457 @default.
• W4283768088 hasConceptScore W4283768088C161790260 @default.
• W4283768088 hasConceptScore W4283768088C171250308 @default.
• W4283768088 hasConceptScore W4283768088C175583648 @default.
• W4283768088 hasConceptScore W4283768088C178790620 @default.
• W4283768088 hasConceptScore W4283768088C185592680 @default.
• W4283768088 hasConceptScore W4283768088C192562407 @default.
• W4283768088 hasConceptScore W4283768088C2775871042 @default.

• next