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- W4283776626 abstract "Abstract Palladium(II) hydroxide on carbon is a catalyst routinely used for the cleavage of O‐benzyl groups by hydrogenolysis to obtain the corresponding parent organic compound. The work described in this article shows that allyl and benzyl phosphates, can be cleaved efficiently and selectively using palladium(II) hydroxide on carbon, under non‐hydrogenolytic and neutral conditions, precluding the migration of acyl groups. The utility of these cleavage reactions for the synthesis of diacylglycerol and phosphatidic acid, containing unsaturation, is demonstrated. These methods have high potential for the synthesis of a variety of phosphates and natural phospholipids." @default.
- W4283776626 created "2022-07-03" @default.
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- W4283776626 date "2022-07-01" @default.
- W4283776626 modified "2023-09-26" @default.
- W4283776626 title "Palladium Mediated Selective Cleavage of Benzyl and Allyl Phosphates: A Convenient Non‐Hydrogenolytic Method for the Synthesis of Phosphates and Phospholipids." @default.
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- W4283776626 doi "https://doi.org/10.1002/slct.202201167" @default.
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