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• W4283791681 abstract "Abstract Base treatment and metal doping were evaluated as means of enhancing the photocatalytic activity of ZrO 2 nanoparticles (NPs) via the generation of oxygen vacancies (O vS ), and the sites responsible for this enhancement were identified and characterized by spectroscopic and microscopic techniques. We confirmed that O vS produced by base treatment engaged in photocatalytic activity for organic pollutant degradation, whereas surface defects introduced by Cr-ion doping engaged in oxidative catalysis of molecules. Moreover, we verified that base-treated ZrO 2 NPs outperformed their Cr-ion doped counterparts as photocatalysts using in situ X-ray photoelectron spectroscopy and scanning transmission electron microscopy coupled with electron energy loss spectroscopy (STEM-EELS). Thus, our study provides valuable information on the origin of the enhanced photocatalytic activity of modified ZrO 2 NPs and demonstrates the practicality of in situ spectroscopy and STEM-EELS for the evaluation of highly efficient metal oxide photocatalysts." @default.
• W4283791681 created "2022-07-05" @default.
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• W4283791681 date "2022-07-04" @default.
• W4283791681 modified "2023-10-16" @default.
• W4283791681 title "Verifying the relationships of defect site and enhanced photocatalytic properties of modified ZrO2 nanoparticles evaluated by in-situ spectroscopy and STEM-EELS" @default.
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• W4283791681 doi "https://doi.org/10.1038/s41598-022-15557-0" @default.
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• W4283791681 hasPublicationYear "2022" @default.
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