Matches in SemOpenAlex for { <https://semopenalex.org/work/W4284668876> ?p ?o ?g. }
- W4284668876 abstract "Abstract Carbenes, including N ‐heterocyclic carbene (NHC) ligands, are used extensively to stabilize open‐shell transition metal complexes and organic radicals. Yet, it remains unknown, which carbene stabilizes a radical well and, thus, how to design radical‐stabilizing C‐donor ligands. With the large variety of C‐donor ligands experimentally investigated and their electronic properties established, we report herein their radical‐stabilizing effect. We show that radical stabilization can be understood by a captodative frontier orbital description involving π‐donation to‐ and π‐donation from the carbenes. This picture sheds a new perspective on NHC chemistry, where π‐donor effects usually are assumed to be negligible. Further, it allows for the intuitive prediction of the thermodynamic stability of covalent radicals of main group‐ and transition metal carbene complexes, and the quantification of redox non‐innocence." @default.
- W4284668876 created "2022-07-08" @default.
- W4284668876 creator A5003935031 @default.
- W4284668876 creator A5020271560 @default.
- W4284668876 creator A5059734226 @default.
- W4284668876 creator A5075139712 @default.
- W4284668876 date "2022-08-04" @default.
- W4284668876 modified "2023-09-30" @default.
- W4284668876 title "Gauging Radical Stabilization with Carbenes" @default.
- W4284668876 cites W1250165004 @default.
- W4284668876 cites W1831340365 @default.
- W4284668876 cites W1837410261 @default.
- W4284668876 cites W1966983316 @default.
- W4284668876 cites W196704371 @default.
- W4284668876 cites W1969782821 @default.
- W4284668876 cites W1971080513 @default.
- W4284668876 cites W1973383114 @default.
- W4284668876 cites W1974404779 @default.
- W4284668876 cites W1975592132 @default.
- W4284668876 cites W1979410966 @default.
- W4284668876 cites W1980891092 @default.
- W4284668876 cites W1981090061 @default.
- W4284668876 cites W1982567581 @default.
- W4284668876 cites W1983900744 @default.
- W4284668876 cites W1988091937 @default.
- W4284668876 cites W1988716453 @default.
- W4284668876 cites W1989389552 @default.
- W4284668876 cites W1991588461 @default.
- W4284668876 cites W1996823187 @default.
- W4284668876 cites W1998732907 @default.
- W4284668876 cites W1999387838 @default.
- W4284668876 cites W2002645636 @default.
- W4284668876 cites W2003286577 @default.
- W4284668876 cites W2004575088 @default.
- W4284668876 cites W2005835349 @default.
- W4284668876 cites W2008844584 @default.
- W4284668876 cites W2014086481 @default.
- W4284668876 cites W2016812564 @default.
- W4284668876 cites W2018674598 @default.
- W4284668876 cites W2018891639 @default.
- W4284668876 cites W2019606902 @default.
- W4284668876 cites W2021706783 @default.
- W4284668876 cites W2023271753 @default.
- W4284668876 cites W2025945778 @default.
- W4284668876 cites W2026192027 @default.
- W4284668876 cites W2026272870 @default.
- W4284668876 cites W2028160394 @default.
- W4284668876 cites W2031849738 @default.
- W4284668876 cites W2032757769 @default.
- W4284668876 cites W2034270729 @default.
- W4284668876 cites W2035910400 @default.
- W4284668876 cites W2038442961 @default.
- W4284668876 cites W2039293281 @default.
- W4284668876 cites W2043304555 @default.
- W4284668876 cites W2045862135 @default.
- W4284668876 cites W2046286719 @default.
- W4284668876 cites W2046580220 @default.
- W4284668876 cites W2047937197 @default.
- W4284668876 cites W2048875054 @default.
- W4284668876 cites W2051891162 @default.
- W4284668876 cites W2052837926 @default.
- W4284668876 cites W2052842895 @default.
- W4284668876 cites W2053479907 @default.
- W4284668876 cites W2054845731 @default.
- W4284668876 cites W2060943125 @default.
- W4284668876 cites W2061227309 @default.
- W4284668876 cites W2061830723 @default.
- W4284668876 cites W2063701427 @default.
- W4284668876 cites W2064813419 @default.
- W4284668876 cites W2067718414 @default.
- W4284668876 cites W2072131711 @default.
- W4284668876 cites W2074019461 @default.
- W4284668876 cites W2074035162 @default.
- W4284668876 cites W2078511427 @default.
- W4284668876 cites W2080065789 @default.
- W4284668876 cites W2081224247 @default.
- W4284668876 cites W2083357654 @default.
- W4284668876 cites W2087864238 @default.
- W4284668876 cites W2088051707 @default.
- W4284668876 cites W2090491384 @default.
- W4284668876 cites W2091687583 @default.
- W4284668876 cites W2091692227 @default.
- W4284668876 cites W2092157292 @default.
- W4284668876 cites W2092708351 @default.
- W4284668876 cites W2093733210 @default.
- W4284668876 cites W2096747776 @default.
- W4284668876 cites W2097508537 @default.
- W4284668876 cites W2101958915 @default.
- W4284668876 cites W2102862096 @default.
- W4284668876 cites W2103029770 @default.
- W4284668876 cites W2103660943 @default.
- W4284668876 cites W2105492427 @default.
- W4284668876 cites W2108132042 @default.
- W4284668876 cites W2115186519 @default.
- W4284668876 cites W2120384445 @default.
- W4284668876 cites W2122031375 @default.
- W4284668876 cites W2124491076 @default.
- W4284668876 cites W2127265726 @default.
- W4284668876 cites W2131498189 @default.
- W4284668876 cites W2131937366 @default.