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- W4284889669 endingPage "4369" @default.
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- W4284889669 abstract "A series of C3-symmetric fully substituted benzenes were prepared based on alkyl triamino-benzene-tricarboxylates. Starting with a one step-synthesis, the alkyl triamino-benzene-tricarboxylates were synthesized using the corresponding cyanoacetates. The reactivity of these electronically sophisticated compounds was investigated by the formation of azides, the click reaction of the azides and a Sandmeyer-like reaction. Caused by the low stability of triaminobenzenes, direct N-alkylation was rarely reported. The use of the stable alkyl triamino-benzene-tricarboxylates allowed us total N-alkylation under standard alkylation conditions. The molecular structures of the C3-symmetric structures have been corroborated by an X-ray analysis." @default.
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- W4284889669 date "2022-07-07" @default.
- W4284889669 modified "2023-09-30" @default.
- W4284889669 title "Functionalized C3-Symmetric Building Blocks—The Chemistry of Triaminotrimesic Acid" @default.
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- W4284889669 doi "https://doi.org/10.3390/molecules27144369" @default.
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