Matches in SemOpenAlex for { <https://semopenalex.org/work/W4284898032> ?p ?o ?g. }
- W4284898032 endingPage "11496" @default.
- W4284898032 startingPage "11484" @default.
- W4284898032 abstract "Five new mononuclear lanthanide complexes, [LnL2][Et3NH]·THF/H2O (Ln = Nd, Tb, Dy) (H2LCl = 2-bis(2-hydroxy-3,5-dichloro benzyl)aminomethyl]pyridine), Ln = Nd (1), Tb (2), and Dy (3), and (H2LBr = 2-bis(2-hydroxy-3,5-dibromo benzyl)aminomethyl]pyridine), Ln = Nd (4, H2O) and Tb (5), were synthesized and structurally characterized by single-crystal X-ray diffraction analyses. Being isostructural in all the five cases, the metal center is octa-coordinated with a triangular dodecahedron (D2d symmetry) geometry, and it is independent of the halogen substitution (Cl/Br). This close similarity is due to the composite interplay of hydrogen/halogen bond interactions that control the overall crystal packing, yet notable differences in association patterns among the individual ones arise from the subtle stereo-electronic requirement of individual molecules in the three-dimensional (3D) architecture. Hirshfeld surface and density functional theory (DFT) calculations clearly vouch for the importance of the hydrogen bond and halogen bond interactions observed in the structure. Detailed magnetic measurements using direct-current and alternating-current susceptibility measurements show slow magnetic relaxation in 3, a characteristic feature of the single-molecule magnets (SMMs), which is not shown by 1 and 2. Steady-state and time-resolved photoluminescence of Tb(III) complexes shows a strong ligand-to-metal energy transfer that can be modulated by changing the substitution on phenolic ligands. The results from these analyses indicate that it may be advantageous to consider the subtle role of hydrogen bond (HB)/halogen bond (XB) intermolecular interactions judiciously for the design of SMMs and luminescent materials based on halogen-substituted ligands." @default.
- W4284898032 created "2022-07-09" @default.
- W4284898032 creator A5001912162 @default.
- W4284898032 creator A5016269379 @default.
- W4284898032 creator A5031950776 @default.
- W4284898032 creator A5038187067 @default.
- W4284898032 creator A5056396186 @default.
- W4284898032 creator A5057598354 @default.
- W4284898032 creator A5066837417 @default.
- W4284898032 creator A5075092432 @default.
- W4284898032 creator A5081621810 @default.
- W4284898032 creator A5089715005 @default.
- W4284898032 creator A5054944777 @default.
- W4284898032 date "2022-07-08" @default.
- W4284898032 modified "2023-10-16" @default.
- W4284898032 title "Halogen Bond Mediated Self-Assembly of Mononuclear Lanthanide Complexes: Perception of Supramolecular Interactions, Slow Magnetic Relaxation, and Photoluminescence Properties" @default.
- W4284898032 cites W1905183855 @default.
- W4284898032 cites W1968339413 @default.
- W4284898032 cites W1971152942 @default.
- W4284898032 cites W1978239898 @default.
- W4284898032 cites W1978964278 @default.
- W4284898032 cites W1979303409 @default.
- W4284898032 cites W1988765559 @default.
- W4284898032 cites W1994613702 @default.
- W4284898032 cites W2003967097 @default.
- W4284898032 cites W2012488984 @default.
- W4284898032 cites W2016890925 @default.
- W4284898032 cites W2027162609 @default.
- W4284898032 cites W2033766210 @default.
- W4284898032 cites W2034128569 @default.
- W4284898032 cites W2042397184 @default.
- W4284898032 cites W2053974300 @default.
- W4284898032 cites W2062949409 @default.
- W4284898032 cites W2063334178 @default.
- W4284898032 cites W2071955309 @default.
- W4284898032 cites W2080665513 @default.
- W4284898032 cites W2082523602 @default.
- W4284898032 cites W2088631981 @default.
- W4284898032 cites W2089740902 @default.
- W4284898032 cites W2093880244 @default.
- W4284898032 cites W2096058748 @default.
- W4284898032 cites W2100700871 @default.
- W4284898032 cites W2101846026 @default.
- W4284898032 cites W2110946497 @default.
- W4284898032 cites W2112958597 @default.
- W4284898032 cites W2116195309 @default.
- W4284898032 cites W2120211519 @default.
- W4284898032 cites W2120590130 @default.
- W4284898032 cites W2143402290 @default.
- W4284898032 cites W2152591818 @default.
- W4284898032 cites W2152969498 @default.
- W4284898032 cites W2157363131 @default.
- W4284898032 cites W2261682921 @default.
- W4284898032 cites W2278348890 @default.
- W4284898032 cites W2323792050 @default.
- W4284898032 cites W2325832631 @default.
- W4284898032 cites W2507962329 @default.
- W4284898032 cites W2603875472 @default.
- W4284898032 cites W2755051534 @default.
- W4284898032 cites W2790268956 @default.
- W4284898032 cites W2791736661 @default.
- W4284898032 cites W2809007097 @default.
- W4284898032 cites W2888698646 @default.
- W4284898032 cites W2891184492 @default.
- W4284898032 cites W2901914536 @default.
- W4284898032 cites W2907288612 @default.
- W4284898032 cites W2908660866 @default.
- W4284898032 cites W2944122478 @default.
- W4284898032 cites W2998928272 @default.
- W4284898032 cites W3015072521 @default.
- W4284898032 cites W3037303114 @default.
- W4284898032 cites W4246198245 @default.
- W4284898032 cites W4248052365 @default.
- W4284898032 doi "https://doi.org/10.1021/acs.inorgchem.2c02004" @default.
- W4284898032 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35801575" @default.
- W4284898032 hasPublicationYear "2022" @default.
- W4284898032 type Work @default.
- W4284898032 citedByCount "3" @default.
- W4284898032 countsByYear W42848980322023 @default.
- W4284898032 crossrefType "journal-article" @default.
- W4284898032 hasAuthorship W4284898032A5001912162 @default.
- W4284898032 hasAuthorship W4284898032A5016269379 @default.
- W4284898032 hasAuthorship W4284898032A5031950776 @default.
- W4284898032 hasAuthorship W4284898032A5038187067 @default.
- W4284898032 hasAuthorship W4284898032A5054944777 @default.
- W4284898032 hasAuthorship W4284898032A5056396186 @default.
- W4284898032 hasAuthorship W4284898032A5057598354 @default.
- W4284898032 hasAuthorship W4284898032A5066837417 @default.
- W4284898032 hasAuthorship W4284898032A5075092432 @default.
- W4284898032 hasAuthorship W4284898032A5081621810 @default.
- W4284898032 hasAuthorship W4284898032A5089715005 @default.
- W4284898032 hasConcept C112887158 @default.
- W4284898032 hasConcept C115624301 @default.
- W4284898032 hasConcept C116569031 @default.
- W4284898032 hasConcept C120665830 @default.
- W4284898032 hasConcept C121332964 @default.
- W4284898032 hasConcept C145148216 @default.
- W4284898032 hasConcept C166950319 @default.