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- W4284960817 abstract "The mechanism of polymorph selection is still not fully understood in crystallization. This study demonstrates the impact of Taylor vortex flow on the crystallization and polymorph selection of l-glutamic acid as an organic model compound. Our results show that amorphous intermediates preceded the formation of a crystalline phase. The morphology of these amorphous precursors─ranging from spherical, oval, and ellipsoidal to irregular shapes─was governed by the velocity of the Taylor vortex flow. We attribute this observation to a transient liquidlike state of the amorphous precursor; simulations indeed corroborated this assumption as the morphology of droplets of a liquidlike precursor varies with the velocity of fluid motion accordingly. The phase selectivity depended on the intensity of the Taylor vortex flow. We found that the metastable α-form crystallized at low Taylor numbers, whereas the thermodynamically stable β-form was obtained at high Taylor numbers, suggesting an impact of Taylor vortex flow on the amorphous-to-crystalline rearrangement of the intermediates. Moreover, a critical value of the Taylor number as Ta ∼ 3636 was determined, which triggered the fast formation of the β-polymorph. We assume that the high shear rate and mass transfer of Taylor vortex flow facilitate the phase transformation from the α- to the β-polymorph." @default.
- W4284960817 created "2022-07-10" @default.
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- W4284960817 date "2022-07-08" @default.
- W4284960817 modified "2023-10-18" @default.
- W4284960817 title "Influence of Taylor Vortex Flow on the Crystallization of <scp>l</scp>-Glutamic Acid as an Organic Model Compound" @default.
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- W4284960817 doi "https://doi.org/10.1021/acs.iecr.2c01505" @default.
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