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- W4285011146 abstract "• Modifications of a CVAAS Hg 0 analyzer suitably for conditions with HCl, NO and NH 3. • No interference of all the modified components and processes to Hg 0 detections. • Consistent Hg 0 measurements with the certified mercury permeation rate. • Fast response to real-time Hg 0 detections even under such harsh conditions. • Stable real-time monitoring of Hg 0 in its catalytic oxidation even at low gas flows. A commercially-available cold-vapor atomic absorption mercury analyzer had many difficulties in monitoring real-time gaseous mercury (Hg 0 ) in its oxidation over a V 2 O 5 /TiO 2 -based catalyst under conditions additionally containing HCl, NO and NH 3 . Thus we made extensive modifications to the original analyzer so that this is suitable for fast and stable real-time Hg 0 detections even at low sample flow rates as well as at the harsh conditions. Our fully modified analyzer gave Hg 0 signals very similar to those based upon the factory-certified permeation rate of the mercury permeation tube. Gaseous Hg 0 could react, only to a small extent, with HCl over a quartz powder and the measured Hg 0 oxidation activity was almost associated with the catalyst depending on concentrations of HCl fed to gas streams with NO and NH 3 . This study can offer useful solutions to academic and industrial research groups to attempt real-time Hg 0 measurements at such chosen conditions." @default.
- W4285011146 created "2022-07-12" @default.
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- W4285011146 date "2022-08-01" @default.
- W4285011146 modified "2023-09-26" @default.
- W4285011146 title "Fast and stable real time monitoring of gaseous mercury in its catalytic oxidation using a fully modified cold-vapor atomic absorption mercury analyzer" @default.
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- W4285011146 doi "https://doi.org/10.1016/j.measurement.2022.111614" @default.
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