Matches in SemOpenAlex for { <https://semopenalex.org/work/W4285011716> ?p ?o ?g. }
- W4285011716 abstract "Polyhydroxyalkanoates (PHAs) are biodegradable and biocompatible polyesters with a wide range of applications; in particular, they currently stand as promising alternatives to conventional polyolefin-based plastics. The introduction of sulfur atoms within the PHAs backbone can endow the resulting polythioesters (PTEs) with differentiated, sometimes enhanced thermal, optical and mechanical properties, thereby widening their versatility and use. Hence, PTEs have been gaining increasing attention over the past half-decade. This review highlights recent advances towards the synthesis of well-defined PTEs by ring-opening polymerization (ROP) of cyclic thioesters - namely thiolactones - as well as of S-carboxyanhydrides and thionolactones; it also covers the ring-opening copolymerization (ROCOP) of cyclic thioanhydrides or thiolactones with epoxides or episulfides. Most of the ROP reactions described are of anionic type, mediated by inorganic, organic or organometallic initiators/catalysts, along with a few enzymatic reactions as well. Emphasis is placed on the reactivity of the thio monomers, in relation to their ring-size ranging from 4- to 5-, 6- and 7-membered cycles, the nature of the catalyst/initiating systems implemented and their efficiency in terms of activity and control over the PTE molar mass, dispersity, topology, and microstructure." @default.
- W4285011716 created "2022-07-12" @default.
- W4285011716 creator A5065859286 @default.
- W4285011716 creator A5074547323 @default.
- W4285011716 creator A5081387676 @default.
- W4285011716 date "2022-07-27" @default.
- W4285011716 modified "2023-10-17" @default.
- W4285011716 title "Polythioesters Prepared by Ring‐Opening Polymerization of Cyclic Thioesters and Related Monomers" @default.
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