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- W4285012120 abstract "Herein, we report an efficient method for the Ni-catalyzed deoxygenative borylation of unprotected phenols and also demonstrate that this Ni-catalyzed phenolic C(sp2)-O transformation is applicable to the Suzuki–Miyaura-type and Heck-type cross-couplings of phenols. Investigations on the reaction intermediate have revealed that the achievement of general, mild deoxygenative cross-coupling reactions of phenols is ascribed to the conversion of phenols into the unusual O-phenyl-uroniums that feature active phenolic C(sp2)-O bonds. The Ni-complex intermediate resulting from an oxidative addition of a phenolic C(sp2)-O bond to monophosphine-supported Ni(0) catalyst was characterized and confirmed to be (PCy3)2Ni(Ar)(F) complex, offering experimental evidence for the generally proposed C(sp2)-O oxidative addition step." @default.
- W4285012120 created "2022-07-12" @default.
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- W4285012120 date "2022-07-11" @default.
- W4285012120 modified "2023-10-13" @default.
- W4285012120 title "Ni-Catalyzed Deoxygenative Borylation of Phenols Via O-Phenyl-uronium Activation" @default.
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- W4285012120 doi "https://doi.org/10.1021/acscatal.2c02708" @default.
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