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- W4285013605 abstract "Soluble sulfur (S8) and insoluble sulfur (IS) have different application fields, and molecular dynamics simulation can reveal their differences in solubility in solvents. It is found that in the simulated carbon disulfide (CS2) solvent, soluble sulfur in the form of clusters mainly promotes the dissolution of clusters through van der Waals interaction between solvent molecules (CS2) and S8, and the solubility gradually increases with the increase in temperature. However, the strong interaction between polymer chains of insoluble sulfur in the form of polymer hinders the diffusion of IS into CS2 solvent, which is not conducive to high-temperature dissolution. The simulated solubility parameter shows that the solubility parameter of soluble sulfur is closer to that of the solvent, which is consistent with the above explanation that soluble sulfur is easy to dissolve." @default.
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- W4285013605 date "2022-07-08" @default.
- W4285013605 modified "2023-10-14" @default.
- W4285013605 title "Molecular Simulation to Explore the Dissolution Behavior of Sulfur in Carbon Disulfide" @default.
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- W4285013605 doi "https://doi.org/10.3390/molecules27144402" @default.
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