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- W4285014368 abstract "A reasonable structural design is essential to suppress the volume expansion of transition metal phosphides and to enhance their electrochemical performance as anode materials for lithium-ion batteries. Herein, a three-dimensional architecture was formed by the carbon nanotubes (CNTs) connected with nitrogen, phosphorus co-doped porous carbon sheets (NPC), in which core-shell-like carbon-coated CoP nanoparticles were uniformly embedded, synthesized [email protected]+CNTs composites with a triple-carbon synergistic cross-linked network structure by a one-step self-templating method. The novel spatial structure effectively suppresses the volume change of CoP, ensures structural stability, and provides a multidimensional pathway for fast ion/electron transport. In addition, the N, P co-doping can synergistically promote the material conductivity and provides plenty of active sites. Profiting from the unique structure, the [email protected]+CNTs anode displays excellent lithium storage performance (1074.5 mAh g−1 at 0.1 A g−1 after 280 cycles), superior rate capacities and long cycle stability (701.7 mAh g−1 at 1.0 A g−1 after 1000 cycles). The simple synthesis method and special structure also provide new ideas for preparing other transition metal phosphides." @default.
- W4285014368 created "2022-07-12" @default.
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- W4285014368 date "2022-10-01" @default.
- W4285014368 modified "2023-10-06" @default.
- W4285014368 title "One-step synthesis of core-shell CoP@ N, P co-doped porous carbon sheet + CNTs: Boosting high-rate/long-life lithium storage via triple-carbon synergistic effects" @default.
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- W4285014368 doi "https://doi.org/10.1016/j.colsurfa.2022.129648" @default.
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