FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4285040114> ?p ?o ?g. }

• W4285040114 endingPage "133680" @default.
• W4285040114 startingPage "133680" @default.
• W4285040114 abstract "2,15-Dibutoxy-6,11-dicyano[6]Helicene (CN-HEL) has been prepared through a two-step sequence under mild conditions, in an overall 78% yield, starting from 2,7-bis(cyanomethyl)naphthalene as a suitable material. The Helicene has been experimentally characterized and its absorption and photoluminescence (PL) properties have been evaluated showing a blue emission in the visible spectrum. A strong absorption is entirely in the UV region (λmax = 290 nm), yet fluorescence occurs at 400 nm. This equates to a Stokes shift of 1.17 eV (9482 cm−1) which is among the largest Stokes shifts reported for small molecules, making it a promising candidate for optoelectronic applications. Furthermore, the 1H NMR, FT-IR, UV-vis and PL spectra were computed by means of the very efficient time-dependent density functional theory (TD-DFT) approach. The computed spectra with two recommended density functional (PBEPBE and cam/B3LYP) and extended basis sets compare very well with the corresponding experimental data. HOMO and LUMO energy levels were also investigated experimentally, showing an electrochemical band gap of 2.54 eV. Results obtained throughout this work are of great importance and prove the relevance of the target Helicene to be used in a wide range of both existing and new applications such as fluorescence probes and molecular sensors." @default.
• W4285040114 created "2022-07-13" @default.
• W4285040114 creator A5003589583 @default.
• W4285040114 creator A5008544079 @default.
• W4285040114 creator A5037039680 @default.
• W4285040114 creator A5046365532 @default.
• W4285040114 creator A5063923356 @default.
• W4285040114 date "2022-11-01" @default.
• W4285040114 modified "2023-10-14" @default.
• W4285040114 title "2,15-dibutoxy-6,11-dicyano[6]Helicene: Synthesis, electrochemical, photophysical properties and computational studies" @default.
• W4285040114 cites W1970561657 @default.
• W4285040114 cites W1986862050 @default.
• W4285040114 cites W1992926979 @default.
• W4285040114 cites W1993940760 @default.
• W4285040114 cites W1995880669 @default.
• W4285040114 cites W2006323418 @default.
• W4285040114 cites W2029667189 @default.
• W4285040114 cites W2048425586 @default.
• W4285040114 cites W2051644999 @default.
• W4285040114 cites W2132525235 @default.
• W4285040114 cites W2139619184 @default.
• W4285040114 cites W2146750546 @default.
• W4285040114 cites W2222240945 @default.
• W4285040114 cites W2311051991 @default.
• W4285040114 cites W2318513966 @default.
• W4285040114 cites W2496618181 @default.
• W4285040114 cites W2520629326 @default.
• W4285040114 cites W2624094034 @default.
• W4285040114 cites W2735927453 @default.
• W4285040114 cites W2925342144 @default.
• W4285040114 cites W2951554252 @default.
• W4285040114 cites W3022075593 @default.
• W4285040114 cites W3049541560 @default.
• W4285040114 cites W3069395969 @default.
• W4285040114 cites W3118805373 @default.
• W4285040114 cites W3138054502 @default.
• W4285040114 cites W3198551882 @default.
• W4285040114 doi "https://doi.org/10.1016/j.molstruc.2022.133680" @default.
• W4285040114 hasPublicationYear "2022" @default.
• W4285040114 type Work @default.
• W4285040114 citedByCount "0" @default.
• W4285040114 crossrefType "journal-article" @default.
• W4285040114 hasAuthorship W4285040114A5003589583 @default.
• W4285040114 hasAuthorship W4285040114A5008544079 @default.
• W4285040114 hasAuthorship W4285040114A5037039680 @default.
• W4285040114 hasAuthorship W4285040114A5046365532 @default.
• W4285040114 hasAuthorship W4285040114A5063923356 @default.
• W4285040114 hasConcept C119824511 @default.
• W4285040114 hasConcept C120665830 @default.
• W4285040114 hasConcept C121332964 @default.
• W4285040114 hasConcept C125287762 @default.
• W4285040114 hasConcept C1276947 @default.
• W4285040114 hasConcept C134121241 @default.
• W4285040114 hasConcept C14158195 @default.
• W4285040114 hasConcept C147597530 @default.
• W4285040114 hasConcept C147789679 @default.
• W4285040114 hasConcept C152365726 @default.
• W4285040114 hasConcept C171001562 @default.
• W4285040114 hasConcept C17525397 @default.
• W4285040114 hasConcept C178790620 @default.
• W4285040114 hasConcept C181966813 @default.
• W4285040114 hasConcept C183152904 @default.
• W4285040114 hasConcept C185592680 @default.
• W4285040114 hasConcept C191897082 @default.
• W4285040114 hasConcept C192562407 @default.
• W4285040114 hasConcept C2780291037 @default.
• W4285040114 hasConcept C32909587 @default.
• W4285040114 hasConcept C4839761 @default.
• W4285040114 hasConcept C49040817 @default.
• W4285040114 hasConcept C52859227 @default.
• W4285040114 hasConcept C75473681 @default.
• W4285040114 hasConcept C80994870 @default.
• W4285040114 hasConcept C85080765 @default.
• W4285040114 hasConcept C91881484 @default.
• W4285040114 hasConceptScore W4285040114C119824511 @default.
• W4285040114 hasConceptScore W4285040114C120665830 @default.
• W4285040114 hasConceptScore W4285040114C121332964 @default.
• W4285040114 hasConceptScore W4285040114C125287762 @default.
• W4285040114 hasConceptScore W4285040114C1276947 @default.
• W4285040114 hasConceptScore W4285040114C134121241 @default.
• W4285040114 hasConceptScore W4285040114C14158195 @default.
• W4285040114 hasConceptScore W4285040114C147597530 @default.
• W4285040114 hasConceptScore W4285040114C147789679 @default.
• W4285040114 hasConceptScore W4285040114C152365726 @default.
• W4285040114 hasConceptScore W4285040114C171001562 @default.
• W4285040114 hasConceptScore W4285040114C17525397 @default.
• W4285040114 hasConceptScore W4285040114C178790620 @default.
• W4285040114 hasConceptScore W4285040114C181966813 @default.
• W4285040114 hasConceptScore W4285040114C183152904 @default.
• W4285040114 hasConceptScore W4285040114C185592680 @default.
• W4285040114 hasConceptScore W4285040114C191897082 @default.
• W4285040114 hasConceptScore W4285040114C192562407 @default.
• W4285040114 hasConceptScore W4285040114C2780291037 @default.
• W4285040114 hasConceptScore W4285040114C32909587 @default.
• W4285040114 hasConceptScore W4285040114C4839761 @default.
• W4285040114 hasConceptScore W4285040114C49040817 @default.
• W4285040114 hasConceptScore W4285040114C52859227 @default.
• W4285040114 hasConceptScore W4285040114C75473681 @default.

• next